Localized electrochemical redox reactions in yttria-stabilized zirconia single crystals

2020
journal article
article
4
cris.lastimport.wos2024-04-10T01:27:50Z
dc.abstract.enHerein, electroreduction in yttria-stabilized zirconia are investigated by means of Hebb-Wagner polarization experiments. By performing optical and thermal microscopy on single crystals and thin films during the application of an electric field under vacuum or oxygen-tight sealed conditions, the movement of the reduction front from the cathode to the anode, which causes a blackening of the material, is monitored. When performing electrocoloration experiments on thin film samples, the progressing reaction of the blackened region was found to be inhomogeneous and evolves as a dendrite-like finger structure. The progression of the blackening fingers follow preferentially the electric field lines and thus are influenced by distortions in the field that can be caused by metallic particles embedded in the oxide. In contrast to this, in the first stage of the reduction process no significant influence of mechanically-induced dislocations on the morphology or kinetics on the electroreduction can be found. Only after a heavy electroreduction was a localized transformation of the surface region observed. There is an evolution of highly oxygen deficient ZrO_{x} regions, which have a characteristic checked topography pattern at the microscale level.pl
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiegopl
dc.contributor.authorRodenbücher, Christianpl
dc.contributor.authorSzot, Kristofpl
dc.contributor.authorWrana, Dominik - 166043 pl
dc.contributor.authorJany, Benedykt - 102112 pl
dc.contributor.authorKrok, Franciszek - 100497 pl
dc.contributor.authorKort, Carstenpl
dc.date.accessioned2020-09-04T13:56:17Z
dc.date.available2020-09-04T13:56:17Z
dc.date.issued2020pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number3pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume2pl
dc.identifier.articleid034008pl
dc.identifier.doi10.1088/2515-7655/ab6b39pl
dc.identifier.eissn2515-7655pl
dc.identifier.projectROD UJ / OPpl
dc.identifier.urihttps://ruj.uj.edu.pl/xmlui/handle/item/245247
dc.languageengpl
dc.language.containerengpl
dc.rightsUdzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa*
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/legalcode.pl*
dc.share.typeotwarte czasopismo
dc.subtypeArticlepl
dc.titleLocalized electrochemical redox reactions in yttria-stabilized zirconia single crystalspl
dc.title.journalJPhys Energypl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-10T01:27:50Z
dc.abstract.enpl
Herein, electroreduction in yttria-stabilized zirconia are investigated by means of Hebb-Wagner polarization experiments. By performing optical and thermal microscopy on single crystals and thin films during the application of an electric field under vacuum or oxygen-tight sealed conditions, the movement of the reduction front from the cathode to the anode, which causes a blackening of the material, is monitored. When performing electrocoloration experiments on thin film samples, the progressing reaction of the blackened region was found to be inhomogeneous and evolves as a dendrite-like finger structure. The progression of the blackening fingers follow preferentially the electric field lines and thus are influenced by distortions in the field that can be caused by metallic particles embedded in the oxide. In contrast to this, in the first stage of the reduction process no significant influence of mechanically-induced dislocations on the morphology or kinetics on the electroreduction can be found. Only after a heavy electroreduction was a localized transformation of the surface region observed. There is an evolution of highly oxygen deficient ZrO_{x} regions, which have a characteristic checked topography pattern at the microscale level.
dc.affiliationpl
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorpl
Rodenbücher, Christian
dc.contributor.authorpl
Szot, Kristof
dc.contributor.authorpl
Wrana, Dominik - 166043
dc.contributor.authorpl
Jany, Benedykt - 102112
dc.contributor.authorpl
Krok, Franciszek - 100497
dc.contributor.authorpl
Kort, Carsten
dc.date.accessioned
2020-09-04T13:56:17Z
dc.date.available
2020-09-04T13:56:17Z
dc.date.issuedpl
2020
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.numberpl
3
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
2
dc.identifier.articleidpl
034008
dc.identifier.doipl
10.1088/2515-7655/ab6b39
dc.identifier.eissnpl
2515-7655
dc.identifier.projectpl
ROD UJ / OP
dc.identifier.uri
https://ruj.uj.edu.pl/xmlui/handle/item/245247
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licence
CC-BY
dc.rights.uri*
http://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.type
otwarte czasopismo
dc.subtypepl
Article
dc.titlepl
Localized electrochemical redox reactions in yttria-stabilized zirconia single crystals
dc.title.journalpl
JPhys Energy
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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