An integrated photocatalytic/enzymatic system for the reduction of to methanol bioglycerol-water

2014
journal article
article
62
cris.lastimport.wos2024-04-10T01:05:19Z
dc.abstract.enA hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorAresta, Michelepl
dc.contributor.authorDibenedetto, Angelapl
dc.contributor.authorBaran, Tomasz - 116886 pl
dc.contributor.authorAngelini, Antonellapl
dc.contributor.authorŁabuz, Przemysław - 135796 pl
dc.contributor.authorMacyk, Wojciech - 130162 pl
dc.date.accession2019-05-13pl
dc.date.accessioned2015-06-22T08:03:13Z
dc.date.available2015-06-22T08:03:13Z
dc.date.issued2014pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.physical2556-2565pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume10pl
dc.identifier.doi10.3762/bjoc.10.267pl
dc.identifier.eissn1860-5397pl
dc.identifier.issn2195-951Xpl
dc.identifier.projectROD UJ / Ppl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/9925
dc.identifier.weblinkhttps://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-267.pdfpl
dc.languageengpl
dc.language.containerengpl
dc.rightsUdzielam licencji. Uznanie autorstwa 2.0*
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/2.0/pl/legalcode*
dc.share.typeotwarte czasopismo
dc.subject.en$CO_2$ chemistrypl
dc.subject.enNADH regenerationpl
dc.subject.enelectron transferpl
dc.subject.enphotochemistrypl
dc.subject.enenzymatic $CO_2$ reductionpl
dc.subject.enphotosensitizationpl
dc.subtypeArticlepl
dc.titleAn integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-waterpl
dc.title.journalBeilstein Journal of Organic Chemistrypl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-10T01:05:19Z
dc.abstract.enpl
A hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.authorpl
Aresta, Michele
dc.contributor.authorpl
Dibenedetto, Angela
dc.contributor.authorpl
Baran, Tomasz - 116886
dc.contributor.authorpl
Angelini, Antonella
dc.contributor.authorpl
Łabuz, Przemysław - 135796
dc.contributor.authorpl
Macyk, Wojciech - 130162
dc.date.accessionpl
2019-05-13
dc.date.accessioned
2015-06-22T08:03:13Z
dc.date.available
2015-06-22T08:03:13Z
dc.date.issuedpl
2014
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.physicalpl
2556-2565
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
10
dc.identifier.doipl
10.3762/bjoc.10.267
dc.identifier.eissnpl
1860-5397
dc.identifier.issnpl
2195-951X
dc.identifier.projectpl
ROD UJ / P
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9925
dc.identifier.weblinkpl
https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-267.pdf
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Udzielam licencji. Uznanie autorstwa 2.0
dc.rights.licence
CC-BY
dc.rights.uri*
http://creativecommons.org/licenses/by/2.0/pl/legalcode
dc.share.type
otwarte czasopismo
dc.subject.enpl
$CO_2$ chemistry
dc.subject.enpl
NADH regeneration
dc.subject.enpl
electron transfer
dc.subject.enpl
photochemistry
dc.subject.enpl
enzymatic $CO_2$ reduction
dc.subject.enpl
photosensitization
dc.subtypepl
Article
dc.titlepl
An integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-water
dc.title.journalpl
Beilstein Journal of Organic Chemistry
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

* The migration of download and view statistics prior to the date of April 8, 2024 is in progress.

Views
12
Views per month
Views per city
Ashburn
3
Dublin
2
Wroclaw
2
Chandler
1
Philadelphia
1
Szczecin
1
Downloads
aresta_dibenedetto_baran_angelini_labuz_macyk_an_integrated_photocatalytic_2014.odt
12
aresta_dibenedetto_baran_angelini_labuz_macyk_an_integrated_photocatalytic_2014.pdf
10