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An integrated photocatalytic/enzymatic system for the reduction of
NADH regeneration
electron transfer
photochemistry
enzymatic
photosensitization
A hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application.
cris.lastimport.wos | 2024-04-10T01:05:19Z | |
dc.abstract.en | A hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application. | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.contributor.author | Aresta, Michele | pl |
dc.contributor.author | Dibenedetto, Angela | pl |
dc.contributor.author | Baran, Tomasz - 116886 | pl |
dc.contributor.author | Angelini, Antonella | pl |
dc.contributor.author | Łabuz, Przemysław - 135796 | pl |
dc.contributor.author | Macyk, Wojciech - 130162 | pl |
dc.date.accession | 2019-05-13 | pl |
dc.date.accessioned | 2015-06-22T08:03:13Z | |
dc.date.available | 2015-06-22T08:03:13Z | |
dc.date.issued | 2014 | pl |
dc.date.openaccess | 0 | |
dc.description.accesstime | w momencie opublikowania | |
dc.description.physical | 2556-2565 | pl |
dc.description.version | ostateczna wersja wydawcy | |
dc.description.volume | 10 | pl |
dc.identifier.doi | 10.3762/bjoc.10.267 | pl |
dc.identifier.eissn | 1860-5397 | pl |
dc.identifier.issn | 2195-951X | pl |
dc.identifier.project | ROD UJ / P | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9925 | |
dc.identifier.weblink | https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-267.pdf | pl |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Udzielam licencji. Uznanie autorstwa 2.0 | * |
dc.rights.licence | CC-BY | |
dc.rights.uri | http://creativecommons.org/licenses/by/2.0/pl/legalcode | * |
dc.share.type | otwarte czasopismo | |
dc.subject.en | $CO_2$ chemistry | pl |
dc.subject.en | NADH regeneration | pl |
dc.subject.en | electron transfer | pl |
dc.subject.en | photochemistry | pl |
dc.subject.en | enzymatic $CO_2$ reduction | pl |
dc.subject.en | photosensitization | pl |
dc.subtype | Article | pl |
dc.title | An integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-water | pl |
dc.title.journal | Beilstein Journal of Organic Chemistry | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |
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Except as otherwise noted, this item is licensed under : Udzielam licencji. Uznanie autorstwa 2.0