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Effect of cobalt doping on the dielectric response of
co-doping
deviation from the Curie-Weisslaw
dielectric properties
Dielectric response of Ba 0.95 Pb 0.05 TiO 3 ceramics doped with 0.1 and 1 wt.% of Co 2 O 3 , synthesized by conven- tional high-temperature method, wa s studied in wide temperature and frequency range. The temperature dependences of the real and the imaginary parts of dielectric permittivity of the ceramics were compared with those of BaTiO 3 and Ba 0.95 Pb 0.05 TiO 3. The addition of Co 3+ ions results in a broadening of dielectric anom- alies related to the transition to p araelectric cubic phase, and the structural transition between the tetragonal and the orthorhombic phases. At low temperatures (125 – 200 K) the dielectric absorp- tion of Co-doped Ba 0.95 Pb 0.05 TiO 3 ceramics was found to exhibit relaxor-like properties. The die lectric response has been found to contain the contributions characte ristic of fluctuations of the polar nanoregion boundaries and reorientations of the dipole moments between allowed directions in the nanoregions in the rhombohe- dral and the orthorhombic phases. The behavior speaks in favor of ordering of polar defects in the host lattice of Ba 0.95 Pb 0.05 TiO 3 in a form polar nanoregions.
cris.lastimport.wos | 2024-04-09T19:13:26Z | |
dc.abstract.en | Dielectric response of Ba 0.95 Pb 0.05 TiO 3 ceramics doped with 0.1 and 1 wt.% of Co 2 O 3 , synthesized by conven- tional high-temperature method, wa s studied in wide temperature and frequency range. The temperature dependences of the real and the imaginary parts of dielectric permittivity of the ceramics were compared with those of BaTiO 3 and Ba 0.95 Pb 0.05 TiO 3. The addition of Co 3+ ions results in a broadening of dielectric anom- alies related to the transition to p araelectric cubic phase, and the structural transition between the tetragonal and the orthorhombic phases. At low temperatures (125 – 200 K) the dielectric absorp- tion of Co-doped Ba 0.95 Pb 0.05 TiO 3 ceramics was found to exhibit relaxor-like properties. The die lectric response has been found to contain the contributions characte ristic of fluctuations of the polar nanoregion boundaries and reorientations of the dipole moments between allowed directions in the nanoregions in the rhombohe- dral and the orthorhombic phases. The behavior speaks in favor of ordering of polar defects in the host lattice of Ba 0.95 Pb 0.05 TiO 3 in a form polar nanoregions. | pl |
dc.affiliation | Wydział Chemii : Zakład Technologii Chemicznej | pl |
dc.contributor.author | Markiewicz, E. | pl |
dc.contributor.author | Bujakiewicz-Korońska, Renata | pl |
dc.contributor.author | Majda, Dorota - 130211 | pl |
dc.contributor.author | Vasylechko, Leonid | pl |
dc.contributor.author | Kalvane, Anna | pl |
dc.contributor.author | Matczak, M. | pl |
dc.date.accession | 2019-02-15 | pl |
dc.date.accessioned | 2015-06-17T08:33:58Z | |
dc.date.available | 2015-06-17T08:33:58Z | |
dc.date.issued | 2014 | pl |
dc.date.openaccess | 0 | |
dc.description.accesstime | w momencie opublikowania | |
dc.description.number | 1 | pl |
dc.description.physical | 92-101 | pl |
dc.description.version | ostateczna wersja wydawcy | |
dc.description.volume | 32 | pl |
dc.identifier.doi | 10.1007/s10832-013-9865-1 | pl |
dc.identifier.eissn | 1573-8663 | pl |
dc.identifier.issn | 1385-3449 | pl |
dc.identifier.project | ROD UJ / P | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9673 | |
dc.identifier.weblink | https://link.springer.com/content/pdf/10.1007%2Fs10832-013-9865-1.pdf | pl |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa | * |
dc.rights.licence | CC-BY | |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/legalcode.pl | * |
dc.share.type | inne | |
dc.subject.en | $B_{0.95}Pb_{0.05}TiO_3$ | pl |
dc.subject.en | co-doping | pl |
dc.subject.en | deviation from the Curie-Weisslaw | pl |
dc.subject.en | dielectric properties | pl |
dc.subtype | Article | pl |
dc.title | Effect of cobalt doping on the dielectric response of $B_{0.95}Pb_{0.05}TiO_3$ ceramics | pl |
dc.title.journal | Journal of Electroceramics | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |
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