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Synthesis and characterization of novel bis-arsenic complexes
2011
journal article
article
Journal
Asian Journal of Chemistry
Author
Arabuli Lili
Matoga Dariusz
Lekishvili Nodar
Volume
23
Issue
7
Pages
2999-3002
ISSN
0970-7077
eISSN
0975-427X
Keywords in English
bis-arsenic complex
tetrahedral configuration
crystal structure
spectral analysis
Access date
2019-03-27
Remarks
Bibliogr. s. 3002.
Language
English
Journal language
English
Abstract in English
p-Phenylenebis[diethyl(iso-propyl)arsonium] tetra-N-thiocyanatocobaltate(II) cationic-anionic complex have been synthesized and studied. The X-ray structure of + [(i-Pr)2(Et)4As2(Ph)]+ [Co(NCS)4] 2- have been determined. Crystals belong to the tetragonal system, space group P-42(1)m) with a = 14.4930(14)Å, b = 14.4930(14)Å, c = 8.7090(19)Å; α = 90°, β = 90°, γ = 90°. The structures were refined to an R value of 0.063 from 4082 observed reflections. The As atom is coordinated tetrahedraly to the substituents as well as the anion has a tetrahedral configuration. The synthesis and IR spectral characterization of the complex compounds are described.
Affiliation
Wydział Chemii : Zakład Chemii Nieorganicznej
| dc.abstract.en | p-Phenylenebis[diethyl(iso-propyl)arsonium] tetra-N-thiocyanatocobaltate(II) cationic-anionic complex have been synthesized and studied. The X-ray structure of + [(i-Pr)2(Et)4As2(Ph)]+ [Co(NCS)4] 2- have been determined. Crystals belong to the tetragonal system, space group P-42(1)m) with a = 14.4930(14)Å, b = 14.4930(14)Å, c = 8.7090(19)Å; α = 90°, β = 90°, γ = 90°. The structures were refined to an R value of 0.063 from 4082 observed reflections. The As atom is coordinated tetrahedraly to the substituents as well as the anion has a tetrahedral configuration. The synthesis and IR spectral characterization of the complex compounds are described. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.contributor.author | Arabuli, Lili | pl |
| dc.contributor.author | Matoga, Dariusz - 130394 | pl |
| dc.contributor.author | Lekishvili, Nodar | pl |
| dc.date.accession | 2019-03-27 | pl |
| dc.date.accessioned | 2019-03-27T07:32:35Z | |
| dc.date.available | 2019-03-27T07:32:35Z | |
| dc.date.issued | 2011 | pl |
| dc.date.openaccess | 0 | |
| dc.description.accesstime | w momencie opublikowania | |
| dc.description.additional | Bibliogr. s. 3002. | pl |
| dc.description.number | 7 | pl |
| dc.description.physical | 2999-3002 | pl |
| dc.description.version | ostateczna wersja wydawcy | |
| dc.description.volume | 23 | pl |
| dc.identifier.eissn | 0975-427X | pl |
| dc.identifier.issn | 0970-7077 | pl |
| dc.identifier.project | ROD UJ / OP | pl |
| dc.identifier.uri | https://ruj.uj.edu.pl/xmlui/handle/item/71475 | |
| dc.identifier.weblink | http://www.asianjournalofchemistry.co.in/User/ViewFreeArticle.aspx?ArticleID=23_7_37 | pl |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights | Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne 4.0 Międzynarodowa | * |
| dc.rights.licence | CC-BY-NC | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/legalcode.pl | * |
| dc.share.type | otwarte czasopismo | |
| dc.subject.en | bis-arsenic complex | pl |
| dc.subject.en | tetrahedral configuration | pl |
| dc.subject.en | crystal structure | pl |
| dc.subject.en | spectral analysis | pl |
| dc.subtype | Article | pl |
| dc.title | Synthesis and characterization of novel bis-arsenic complexes | pl |
| dc.title.journal | Asian Journal of Chemistry | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
dc.abstract.enpl
p-Phenylenebis[diethyl(iso-propyl)arsonium] tetra-N-thiocyanatocobaltate(II) cationic-anionic complex have been synthesized and studied.
The X-ray structure of +
[(i-Pr)2(Et)4As2(Ph)]+
[Co(NCS)4]
2- have been determined. Crystals belong to the tetragonal system, space group
P-42(1)m) with a = 14.4930(14)Å, b = 14.4930(14)Å, c = 8.7090(19)Å; α = 90°, β = 90°, γ = 90°. The structures were refined to an R
value of 0.063 from 4082 observed reflections. The As atom is coordinated tetrahedraly to the substituents as well as the anion has a
tetrahedral configuration. The synthesis and IR spectral characterization of the complex compounds are described. dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej dc.contributor.authorpl
Arabuli, Lili dc.contributor.authorpl
Matoga, Dariusz - 130394 dc.contributor.authorpl
Lekishvili, Nodar dc.date.accessionpl
2019-03-27 dc.date.accessioned
2019-03-27T07:32:35Z dc.date.available
2019-03-27T07:32:35Z dc.date.issuedpl
2011 dc.date.openaccess
0 dc.description.accesstime
w momencie opublikowania dc.description.additionalpl
Bibliogr. s. 3002. dc.description.numberpl
7 dc.description.physicalpl
2999-3002 dc.description.version
ostateczna wersja wydawcy dc.description.volumepl
23 dc.identifier.eissnpl
0975-427X dc.identifier.issnpl
0970-7077 dc.identifier.projectpl
ROD UJ / OP dc.identifier.uri
https://ruj.uj.edu.pl/xmlui/handle/item/71475 dc.identifier.weblinkpl
http://www.asianjournalofchemistry.co.in/User/ViewFreeArticle.aspx?ArticleID=23_7_37 dc.languagepl
eng dc.language.containerpl
eng dc.rights*
Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne 4.0 Międzynarodowa dc.rights.licence
CC-BY-NC dc.rights.uri*
http://creativecommons.org/licenses/by-nc/4.0/legalcode.pl dc.share.type
otwarte czasopismo dc.subject.enpl
bis-arsenic complex dc.subject.enpl
tetrahedral configuration dc.subject.enpl
crystal structure dc.subject.enpl
spectral analysis dc.subtypepl
Article dc.titlepl
Synthesis and characterization of novel bis-arsenic complexes dc.title.journalpl
Asian Journal of Chemistry dc.typepl
JournalArticle dspace.entity.type
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