Influence of dipole–dipole correlations on the stability of the biaxial nematic phase in the model bent-core liquid crystal

2012
journal article
article
12
cris.lastimport.wos2024-04-09T23:14:24Z
dc.abstract.enA molecular theory of biaxial nematic ordering in the system of bent-core molecules has been developed in the two-particle cluster approximation which enables one to take into account short-range polar correlations determined by both electrostatic dipole–dipole interaction and polar molecular shape. All orientational order parameters and short-range correlation functions are calculated numerically as functions of temperature in the uniaxial and in the biaxial nematic phases, and the results are compared with the ones obtained in the mean-field approximation and in the cluster approximation but without taking into consideration the dipole–dipole interaction. It is shown that short-range polar correlations and, in particular, the dipole–dipole correlations dramatically increase the temperature of the transition into the biaxial nematic phase and enhancing its stability range. The results are also very sensitive to the value of the opening angle of a model bent-core molecule.pl
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiegopl
dc.contributor.authorOsipov, Mikhail A.pl
dc.contributor.authorPająk, Grzegorz - 200615 pl
dc.date.accessioned2017-02-28T13:13:33Z
dc.date.available2017-02-28T13:13:33Z
dc.date.issued2012pl
dc.description.number14pl
dc.description.volume24pl
dc.identifier.articleid142201pl
dc.identifier.doi10.1088/0953-8984/24/14/142201pl
dc.identifier.eissn1361-648Xpl
dc.identifier.issn0953-8984pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/39020
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licencebez licencji
dc.rights.uri*
dc.subtypeArticlepl
dc.titleInfluence of dipole–dipole correlations on the stability of the biaxial nematic phase in the model bent-core liquid crystalpl
dc.title.journalJournal of Physics. Condensed Matterpl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T23:14:24Z
dc.abstract.enpl
A molecular theory of biaxial nematic ordering in the system of bent-core molecules has been developed in the two-particle cluster approximation which enables one to take into account short-range polar correlations determined by both electrostatic dipole–dipole interaction and polar molecular shape. All orientational order parameters and short-range correlation functions are calculated numerically as functions of temperature in the uniaxial and in the biaxial nematic phases, and the results are compared with the ones obtained in the mean-field approximation and in the cluster approximation but without taking into consideration the dipole–dipole interaction. It is shown that short-range polar correlations and, in particular, the dipole–dipole correlations dramatically increase the temperature of the transition into the biaxial nematic phase and enhancing its stability range. The results are also very sensitive to the value of the opening angle of a model bent-core molecule.
dc.affiliationpl
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorpl
Osipov, Mikhail A.
dc.contributor.authorpl
Pająk, Grzegorz - 200615
dc.date.accessioned
2017-02-28T13:13:33Z
dc.date.available
2017-02-28T13:13:33Z
dc.date.issuedpl
2012
dc.description.numberpl
14
dc.description.volumepl
24
dc.identifier.articleidpl
142201
dc.identifier.doipl
10.1088/0953-8984/24/14/142201
dc.identifier.eissnpl
1361-648X
dc.identifier.issnpl
0953-8984
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/39020
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
bez licencji
dc.rights.uri*
dc.subtypepl
Article
dc.titlepl
Influence of dipole–dipole correlations on the stability of the biaxial nematic phase in the model bent-core liquid crystal
dc.title.journalpl
Journal of Physics. Condensed Matter
dc.typepl
JournalArticle
dspace.entity.type
Publication
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