EPR investigation of Cu(II)-complexes with nitrogen derivatives of dialdehyde starch

Bibliographic description

punktacja MNiSW [2012 A]: 40

title:	EPR investigation of Cu(II)-complexes with nitrogen derivatives of dialdehyde starch
author:	Łabanowska Maria , Bidzińska Ewa , Para Andrzej, Kurdziel Magdalena
journal title:	Carbohydrate Polymers
volume:	87
issue:	4
date of publication :	2012
pages:	2605-2613
ISSN:	0144-8617
eISSN:	1879-1344
DOI:	10.1016/j.carbpol.2011.11.034
language:	English
journal language:	English
abstract in English:	Dialdehyde starch obtained by periodate oxidation from potato starch was converted into its disemicarbazone (DSC), dithiosemicarbazone (DTSC), dihydrazone (DHZ) and dioxime (DOX). The Cu(II) complexes of these compounds were prepared and characterized by Raman and EPR spectra, as well as by the measurements of magnetic susceptibility. EPR investigations showed that two types of complexes with different surroundings of copper centres existed in each starch derivative. Besides nitrogen atoms of the C=N moiety and sulphur atoms of the C=S moiety, also oxygen atoms from starch hydroxyl groups and/or water molecule were proposed as the coordination sites for the central copper ions.
keywords in English:	EPR of copper complexes, copper complexes structure, nitrogen dialdehyde starch derivatives
affiliation:	Wydział Chemii : Zakład Chemii Nieorganicznej
type:	journal article
subtype:	academic paper

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