Zeolite Y modified with palladium as effective catalyst for selective catalytic oxidation of ammonia to nitrogen

2014
journal article
article
107
cris.lastimport.wos2024-04-09T19:10:14Z
dc.abstract.enZeolites HY modified with palladium (0.05-2.5 wt.%) were found to be active and selective catalysts in the process of the selective oxidation of ammonia to nitrogen (NH3-SCO). Parent zeolite and its modifications with palladium were investigated with regard to their structural, textural, and redox properties. The IR spectroscopy, X-ray diffraction, and BET methods were employed for these purposes. Correlation between loading and aggregation of Pd-species deposited on zeolites and their activity and selectivity in the NH3-SCO process was found. Studies of adsorption forms of ammonia and product of its conversion done by IR spectroscopy as well as catalytic tests performed with various space velocities gave insight into the reaction mechanism. Zeolite Y modified with palladium is an interesting catalyst of selective ammonia oxidation for potential application in diesel car exhaust gas purification system.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.affiliationWydział Chemii : Zakład Technologii Chemicznejpl
dc.affiliationWydział Chemii : Pracownia Spektrometrii w Podczerwienipl
dc.contributor.authorJabłońska, Magdalena - 107656 pl
dc.contributor.authorKról, Annapl
dc.contributor.authorKukulska-Zając, Ewapl
dc.contributor.authorTarach, Karolina - 103685 pl
dc.contributor.authorChmielarz, Lucjan - 127527 pl
dc.contributor.authorGóra-Marek, Kinga - 128133 pl
dc.date.accessioned2015-01-27T15:08:20Z
dc.date.available2015-01-27T15:08:20Z
dc.date.issued2014pl
dc.description.physical36-46pl
dc.description.volume316pl
dc.identifier.doi10.1016/j.jcat.2014.04.022pl
dc.identifier.eissn1090-2694pl
dc.identifier.issn0021-9517pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/2777
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licenceBez licencji otwartego dostępu
dc.rights.uri*
dc.subject.enpalladiumpl
dc.subject.enzeolitespl
dc.subject.enSCOpl
dc.subject.enIR spectroscopypl
dc.subtypeArticlepl
dc.titleZeolite Y modified with palladium as effective catalyst for selective catalytic oxidation of ammonia to nitrogenpl
dc.title.journalJournal of Catalysispl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T19:10:14Z
dc.abstract.enpl
Zeolites HY modified with palladium (0.05-2.5 wt.%) were found to be active and selective catalysts in the process of the selective oxidation of ammonia to nitrogen (NH3-SCO). Parent zeolite and its modifications with palladium were investigated with regard to their structural, textural, and redox properties. The IR spectroscopy, X-ray diffraction, and BET methods were employed for these purposes. Correlation between loading and aggregation of Pd-species deposited on zeolites and their activity and selectivity in the NH3-SCO process was found. Studies of adsorption forms of ammonia and product of its conversion done by IR spectroscopy as well as catalytic tests performed with various space velocities gave insight into the reaction mechanism. Zeolite Y modified with palladium is an interesting catalyst of selective ammonia oxidation for potential application in diesel car exhaust gas purification system.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.affiliationpl
Wydział Chemii : Zakład Technologii Chemicznej
dc.affiliationpl
Wydział Chemii : Pracownia Spektrometrii w Podczerwieni
dc.contributor.authorpl
Jabłońska, Magdalena - 107656
dc.contributor.authorpl
Król, Anna
dc.contributor.authorpl
Kukulska-Zając, Ewa
dc.contributor.authorpl
Tarach, Karolina - 103685
dc.contributor.authorpl
Chmielarz, Lucjan - 127527
dc.contributor.authorpl
Góra-Marek, Kinga - 128133
dc.date.accessioned
2015-01-27T15:08:20Z
dc.date.available
2015-01-27T15:08:20Z
dc.date.issuedpl
2014
dc.description.physicalpl
36-46
dc.description.volumepl
316
dc.identifier.doipl
10.1016/j.jcat.2014.04.022
dc.identifier.eissnpl
1090-2694
dc.identifier.issnpl
0021-9517
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/2777
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
Bez licencji otwartego dostępu
dc.rights.uri*
dc.subject.enpl
palladium
dc.subject.enpl
zeolites
dc.subject.enpl
SCO
dc.subject.enpl
IR spectroscopy
dc.subtypepl
Article
dc.titlepl
Zeolite Y modified with palladium as effective catalyst for selective catalytic oxidation of ammonia to nitrogen
dc.title.journalpl
Journal of Catalysis
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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