Determination of silver traces in pure metallic copper and zinc by a catalytic photometric method

2007
journal article
article
dc.abstract.enDetermination of silver traces in the presence of copper, zinc and sulphate ions by a catalytic method was studied. The highly sensitive method of silver determination is based on the catalytic effect of silver ions on the oxidation of salicylic acid by persulphate in the presence of 2,2'-dipyridyl as an activator. The reaction was followed spectrophotometrically by measuring the rate of change in absorbance with time at 420 nm after 10 min of reagents mixing. The sensitivity, precision and accuracy of the determination of silver traces were investigated in solutions containing excesses of interfering ions. The studied range of interfering ions concentrations was 8 × 10–6 to 2.4 × 10–2 mol dm–3 and corresponds to an amount ratio of interfering to silver ions from 50 to 150 000. The performed analyses showed that the accuracy and precision of silver trace determination by the proposed method is high even in the presence of a huge amount excess of interfering ions. The method was used for quantitative determination of silver contents in a copper foil and in a zinc rod. The obtained results were compared with the analyses performed by FAAS.pl
dc.affiliationWydział Chemii : Zakład Chemii Fizycznej i Elektrochemiipl
dc.contributor.authorSulka, Grzegorz - 132161 pl
dc.contributor.authorJaskuła, Marian - 128495 pl
dc.date.accession2020-12-07pl
dc.date.accessioned2020-12-07T14:24:03Z
dc.date.available2020-12-07T14:24:03Z
dc.date.issued2007pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.additionalBibliogr. s. 150.pl
dc.description.number1pl
dc.description.physical147-150pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume80pl
dc.identifier.eissn1334-417Xpl
dc.identifier.issn0011-1643pl
dc.identifier.projectROD UJ / OPpl
dc.identifier.urihttps://ruj.uj.edu.pl/xmlui/handle/item/258340
dc.identifier.weblinkhttps://hrcak.srce.hr/12837pl
dc.languageengpl
dc.language.containerengpl
dc.rightsUdzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa*
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/legalcode.pl*
dc.share.typeotwarte czasopismo
dc.subject.ensilver tracespl
dc.subject.enkinetics based analytical methodspl
dc.subject.encopper ion interferencepl
dc.subject.enzinc ion interferencepl
dc.subject.ensulphate ion interferencepl
dc.subtypeArticlepl
dc.titleDetermination of silver traces in pure metallic copper and zinc by a catalytic photometric methodpl
dc.title.journalCroatica Chemica Actapl
dc.typeJournalArticlepl
dspace.entity.typePublication
dc.abstract.enpl
Determination of silver traces in the presence of copper, zinc and sulphate ions by a catalytic method was studied. The highly sensitive method of silver determination is based on the catalytic effect of silver ions on the oxidation of salicylic acid by persulphate in the presence of 2,2'-dipyridyl as an activator. The reaction was followed spectrophotometrically by measuring the rate of change in absorbance with time at 420 nm after 10 min of reagents mixing. The sensitivity, precision and accuracy of the determination of silver traces were investigated in solutions containing excesses of interfering ions. The studied range of interfering ions concentrations was 8 × 10–6 to 2.4 × 10–2 mol dm–3 and corresponds to an amount ratio of interfering to silver ions from 50 to 150 000. The performed analyses showed that the accuracy and precision of silver trace determination by the proposed method is high even in the presence of a huge amount excess of interfering ions. The method was used for quantitative determination of silver contents in a copper foil and in a zinc rod. The obtained results were compared with the analyses performed by FAAS.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Fizycznej i Elektrochemii
dc.contributor.authorpl
Sulka, Grzegorz - 132161
dc.contributor.authorpl
Jaskuła, Marian - 128495
dc.date.accessionpl
2020-12-07
dc.date.accessioned
2020-12-07T14:24:03Z
dc.date.available
2020-12-07T14:24:03Z
dc.date.issuedpl
2007
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.additionalpl
Bibliogr. s. 150.
dc.description.numberpl
1
dc.description.physicalpl
147-150
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
80
dc.identifier.eissnpl
1334-417X
dc.identifier.issnpl
0011-1643
dc.identifier.projectpl
ROD UJ / OP
dc.identifier.uri
https://ruj.uj.edu.pl/xmlui/handle/item/258340
dc.identifier.weblinkpl
https://hrcak.srce.hr/12837
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licence
CC-BY
dc.rights.uri*
http://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.type
otwarte czasopismo
dc.subject.enpl
silver traces
dc.subject.enpl
kinetics based analytical methods
dc.subject.enpl
copper ion interference
dc.subject.enpl
zinc ion interference
dc.subject.enpl
sulphate ion interference
dc.subtypepl
Article
dc.titlepl
Determination of silver traces in pure metallic copper and zinc by a catalytic photometric method
dc.title.journalpl
Croatica Chemica Acta
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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