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Quantitative IR studies of the concentration of
CoZSM-5
CoFER
IR spectroscopy
absorption coefficient
Quantitative IR experiments were realized to determine the concentration of cobalt in a form of trivalent cations being in the oxide form as well as divalent ions in exchange positions, oxide-like clusters and cobalt oxide, present in a series of cobalt-exchanged zeolites. The first step of such quantitative studies was to elaborate the experimental conditions in which probe molecules NO and CO should react selectively with either of these sites. Subsequently, the values of absorption coefficients of the 1940
cris.lastimport.scopus | 2024-04-07T17:15:08Z | |
cris.lastimport.wos | 2024-04-10T00:19:01Z | |
dc.abstract.en | Quantitative IR experiments were realized to determine the concentration of cobalt in a form of trivalent cations being in the oxide form as well as divalent ions in exchange positions, oxide-like clusters and cobalt oxide, present in a series of cobalt-exchanged zeolites. The first step of such quantitative studies was to elaborate the experimental conditions in which probe molecules NO and CO should react selectively with either of these sites. Subsequently, the values of absorption coefficients of the 1940$cm^{-1}$ band of $Co^{3+}$–NO and the 2204$cm^{-1}$ band of $Co^{2+}$–CO for $Co^{2+}$ in exchange positions, together with the 2194$cm^{-1}$ band of $Co^{2+}$–CO for $Co^{2+}$ in oxide-like clusters were determined. The linear plots of the band intensities versus the concentration of NO and CO interacting with cationic sites showed the correlation coefficients higher than 0.99. Three zeolites were investigated: CoZSM-5 (Si/Al = 15) in which most of $Co^{2+}$ occupied the exchange positions, CoZSM-5 (Si/Al = 40) in which most of $Co^{2+}$ was in the form of oxide-like clusters and CoO, and CoFER prepared by the contact-induced ion exchange with nearly equal amount of $Co^{2+}$ in either type of the sites. The sum of the concentration of Co sites ($Co^{3+}$ and $Co^{2+}$) determined by IR spectroscopy was very close to the values obtained from the chemical analysis (AAS). The concentration ill-defined oxide form of $Co^{3+}$ was surprisingly high as in CoZSM-5 of Si/Al = 15 it constituted about half of the overall cobalt content, and in CoFER the contribution of $Co^{3+}$ reached almost 30%. | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.contributor.author | Góra-Marek, Kinga - 128133 | pl |
dc.contributor.author | Gil, Barbara - 128059 | pl |
dc.contributor.author | Datka, Jerzy - 127692 | pl |
dc.date.accessioned | 2015-09-25T12:44:28Z | |
dc.date.available | 2015-09-25T12:44:28Z | |
dc.date.issued | 2009 | pl |
dc.description.number | 1 | pl |
dc.description.physical | 117-122 | pl |
dc.description.volume | 353 | pl |
dc.identifier.doi | 10.1016/j.apcata.2008.10.034 | pl |
dc.identifier.eissn | 1873-3875 | pl |
dc.identifier.issn | 0926-860X | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/15800 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Dodaję tylko opis bibliograficzny | * |
dc.rights.licence | bez licencji | |
dc.rights.uri | * | |
dc.subject.en | CoZSM-5 | pl |
dc.subject.en | CoFER | pl |
dc.subject.en | IR spectroscopy | pl |
dc.subject.en | absorption coefficient | pl |
dc.subtype | Article | pl |
dc.title | Quantitative IR studies of the concentration of $Co^{2+}$ and $Co^{3+}$ sites in zeolites CoZSM-5 and CoFER | pl |
dc.title.journal | Applied Catalysis. A, General | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |