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Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species
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Skeletal vibrations in CoZSM-5 affected by adsorbed ...
Bibliographic description
| title: | Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species |
| author: | Góra-Marek Kinga 
|
| Journal title: | Journal of Molecular Structure |
| volume: | 892 |
| issue: | 1-3 |
| date of publication: | 2008 |
| pages: | 331-335 |
| ISSN: |
0022-2860 |
| eISSN: |
1872-8014 |
| DOI: | |
| language: | English |
| Journal language: | English |
| abstract in english: | The interaction of adsorbed probe molecules with Co2+ cations in exchange position were investigated in the skeletal transmission window region. The position of the band of oxygen ring perturbed by Co2+ provides information on the electron-acceptor properties of cation as well as the strength of interaction of cation with framework oxygens and with adsorbed molecules. The interaction of Co2+ with CO, NO, H2O, ammonia, acetylene, ethene, benzene and formaldehyde was investigated. The role of σ donation and π back donation in the interaction of CO and organic molecules was discussed. |
| keywords in english: | IR spectroscopy, zeolite CoZSM-5, skeletal vibrations |
| affiliation: | Wydział Chemii : Zakład Chemii Nieorganicznej |
| type: | journal article |
| subtype: | academic paper |
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