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Fourier transform infrared and raman and surface-enhanced raman spectroscopy studies of a novel group of boron analogues of aminophosphonic acids
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Fourier transform infrared and raman and surface-enhanced raman spectroscopy studies of a novel group of boron analogues of aminophosphonic acids
Bibliographic description
| title: | Fourier transform infrared and raman and surface-enhanced raman spectroscopy studies of a novel group of boron analogues of aminophosphonic acids |
| author: | Piergies Natalia  , Proniewicz Edyta , Kudelski Andrzej, Rydzewska Agata, Kim Younkyoo, Andrzejak Marcin , Proniewicz Leonard
|
| journal title: | The Journal of Physical Chemistry. A |
| volume: | 116 |
| issue: | 40 |
| date of publication : | 2012 |
| pages: | 10004-10014 |
| ISSN: |
1089-5639 |
| eISSN: |
1520-5215 |
| DOI: | |
| language: | English |
| journal language: | English |
| abstract in English: | Five analogues of a novel group of boron derivatives of aminophosphonic acids N -benzylamino-(3- boronphenyl)- S -methylphosphonic acid ( m -Ph S ), N -benzyla- mino-(4-boronphenyl)- S -methylphosphonic acid ( p -Ph S ), N - benzylamino-(2-boronphenyl)- R -methylphosphonic acid ( o - Ph R ), N -benzylamino-(3-boronphenyl)- R -methylphosphonic acid ( m -Ph R ), and N -benzylamino-(4-boronphenyl)- R -meth- ylphosphonic acid ( p -Ph R ) were studied using Fourier transform infrared (FT IR), Fourier transform Raman (FT RS), and surface-enhanced Raman (SERS) spectroscopies. Analysis of obtained FT IR and FT RS spectra show that all investigated compounds in the solid state exist as dimeric species formed by an H-bonding interaction between − B(OH) 2 moieties of each monomer. In addition, comparison of the wavenumbers, intensities, and broadness of bands from the FT Raman and SERS spectra allowed information to be obtained regarding the adsorption geometry of the investigated compounds immobilized onto an electrochemically roughened silver substrate. |
| departmental parameterization: | 35 |
| affiliation: | Wydział Chemii : Zakład Fizyki Chemicznej, Wydział Chemii : Zakład Chemii Teoretycznej im. K. Gumińskiego |
| type: | journal article |
| subtype: | academic paper |
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Projekt „Repozytorium otwartego dostępu do dorobku naukowego i dydaktycznego UJ” współfinansowany w ramach poddziałania 2.3.1 „Cyfrowe udostępnianie zasobów nauki” Programu Operacyjnego Polska Cyfrowa z Europejskiego Funduszu Rozwoju Regionalnego i budżetu państwa na podstawie umowy o dofinansowanie nr POPC.02.03.01-00-0030/17-00
