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Copper ionic pairs as possible active sites in
Journal
Catalysis Today
Author
Adamski Andrzej
Zając Wojciech
Zasada Filip
Sojka Zbigniew
Volume
191
Number
1
Title of volume
Nitrogen Oxides Emission Abatement Symposium (NOEA)
Pages
129-133
ISSN
0920-5861
eISSN
1873-4308
Keywords in English
ionic pairs
EPR
DFT
Language
English
Journal language
English
Abstract in English
Synthesized
by
impregnation
and
coprecipitation
methods,
ceria-supported
copper
samples
were
tested
in
catalytic
decomposition
of
Affiliation
Wydział Chemii : Zakład Chemii NieorganicznejWydział Chemii : Zakład Chemii Środowiska
Scopus© citations
29
| dc.abstract.en | Synthesized by impregnation and coprecipitation methods, ceria-supported copper samples were tested in catalytic decomposition of $N_{2}O (deN_{2}O)$ under dry and wet conditions. Basing on the structural (XRD, SEM), spectroscopic (EPR, RS) and catalytic characterization, supported by DFT calculations, the role of mono- and dimeric copper as active centers in the $deN_{2}O$ reaction was evaluated. Particular attention was paid to elucidation of the structure and localization of the $Cu^{2+}$ - $Cu^{2+}$ pairs within the $CeO_{2}$ matrix, their stability and chemical conditions of their formation. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Środowiska | pl |
| dc.contributor.author | Adamski, Andrzej - 127117 | pl |
| dc.contributor.author | Zając, Wojciech | pl |
| dc.contributor.author | Zasada, Filip - 200610 | pl |
| dc.contributor.author | Sojka, Zbigniew - 131982 | pl |
| dc.date.accessioned | 2015-09-10T10:53:41Z | |
| dc.date.available | 2015-09-10T10:53:41Z | |
| dc.date.issued | 2012 | pl |
| dc.description.number | 1 | pl |
| dc.description.physical | 129-133 | pl |
| dc.description.volume | 191 | pl |
| dc.identifier.doi | 10.1016/j.cattod.2012.01.022 | pl |
| dc.identifier.eissn | 1873-4308 | pl |
| dc.identifier.issn | 0920-5861 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/15525 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights | Dodaję tylko opis bibliograficzny | * |
| dc.rights.licence | Bez licencji otwartego dostępu | |
| dc.rights.uri | * | |
| dc.subject.en | $CuO_x/CeO_2$ | pl |
| dc.subject.en | $N_2O$ decomposition | pl |
| dc.subject.en | ionic pairs | pl |
| dc.subject.en | EPR | pl |
| dc.subject.en | DFT | pl |
| dc.subtype | Article | pl |
| dc.title | Copper ionic pairs as possible active sites in $N_{2}O$ decomposition on $CuO_{x}/CeO_{2}$ catalysts | pl |
| dc.title.journal | Catalysis Today | pl |
| dc.title.volume | Nitrogen Oxides Emission Abatement Symposium (NOEA) | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
dc.abstract.enpl
Synthesized
by
impregnation
and
coprecipitation
methods,
ceria-supported
copper
samples
were
tested
in
catalytic
decomposition
of $N_{2}O (deN_{2}O)$
under
dry
and
wet
conditions.
Basing
on
the
structural
(XRD,
SEM),
spectroscopic
(EPR,
RS)
and
catalytic
characterization,
supported
by
DFT
calculations,
the
role
of
mono-
and
dimeric
copper
as
active
centers
in
the
$deN_{2}O$
reaction
was
evaluated.
Particular
attention
was
paid
to
elucidation
of
the
structure
and
localization
of
the
$Cu^{2+}$ - $Cu^{2+}$
pairs
within
the
$CeO_{2}$
matrix,
their
stability
and
chemical
conditions
of
their
formation. dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej dc.affiliationpl
Wydział Chemii : Zakład Chemii Środowiska dc.contributor.authorpl
Adamski, Andrzej - 127117 dc.contributor.authorpl
Zając, Wojciech dc.contributor.authorpl
Zasada, Filip - 200610 dc.contributor.authorpl
Sojka, Zbigniew - 131982 dc.date.accessioned
2015-09-10T10:53:41Z dc.date.available
2015-09-10T10:53:41Z dc.date.issuedpl
2012 dc.description.numberpl
1 dc.description.physicalpl
129-133 dc.description.volumepl
191 dc.identifier.doipl
10.1016/j.cattod.2012.01.022 dc.identifier.eissnpl
1873-4308 dc.identifier.issnpl
0920-5861 dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/15525 dc.languagepl
eng dc.language.containerpl
eng dc.rights*
Dodaję tylko opis bibliograficzny dc.rights.licence
Bez licencji otwartego dostępu dc.rights.uri*
dc.subject.enpl
$CuO_x/CeO_2$ dc.subject.enpl
$N_2O$ decomposition dc.subject.enpl
ionic pairs dc.subject.enpl
EPR dc.subject.enpl
DFT dc.subtypepl
Article dc.titlepl
Copper ionic pairs as possible active sites in $N_{2}O$ decomposition on $CuO_{x}/CeO_{2}$ catalysts dc.title.journalpl
Catalysis Today dc.title.volumepl
Nitrogen Oxides Emission Abatement Symposium (NOEA) dc.typepl
JournalArticle dspace.entity.type
Publication Affiliations
Wydział Chemii
Adamski, Andrzej
Zasada, Filip
Sojka, Zbigniew
No affiliation
Zając, Wojciech
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