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P-C cross-coupling onto enamides : versatile synthesis of -enamido phosphane derivatives

2012
journal article
article
10.1002/ejoc.201101293
Journal
European Journal of Organic Chemistry
Author
Cieślikiewicz-Bouet Monika

Bouet Alexis

Jugé Sylvain

Toffano Martial

Bayardon Jérôme
Show more
Volume
2012
Issue
6
Pages
1101-1106
ISSN
1434-193X
eISSN
1099-0690
Keywords in English

cross-coupling

enols

phosphaalkenes

phosphanes

boranes

Remarks

Na publikacji autorka Cieślikiewicz-Bouet Monika podpisana jako Cieślikiewicz Monika.

Language
English
Journal language
English
Abstract in English

We report herein the Pd-catalyzed P-C cross-coupling reac- tion between enol phosphates and secondary phosphane–bor- ane complexes or phosphane oxides. The reaction was per- formed under mild conditions, owing to Pd activation of the P-H bonds of the phosphane–boranes (or phosphane oxides) and to the powerful enol phosphate coupling reagents. New useful chiral and achiral --alkenylphosphane derivatives bearing an amido group in the -position to the P center were obtained in yields up to 70 %.

Affiliation
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki
Scopus© citations
30
cris.lastimport.wos2024-04-10T00:23:03Z
dc.abstract.enWe report herein the Pd-catalyzed P-C cross-coupling reac- tion between enol phosphates and secondary phosphane–bor- ane complexes or phosphane oxides. The reaction was per- formed under mild conditions, owing to Pd activation of the P-H bonds of the phosphane–boranes (or phosphane oxides) and to the powerful enol phosphate coupling reagents. New useful chiral and achiral $\alpha$-$\beta$-alkenylphosphane derivatives bearing an amido group in the $\alpha$-position to the P center were obtained in yields up to 70 %.pl
dc.affiliationWydział Chemii : Zakład Krystalochemii i Krystalofizykipl
dc.contributor.authorCieślikiewicz-Bouet, Monika - 126193 pl
dc.contributor.authorBouet, Alexispl
dc.contributor.authorJugé, Sylvainpl
dc.contributor.authorToffano, Martialpl
dc.contributor.authorBayardon, Jérômepl
dc.contributor.authorWest, Carolinepl
dc.contributor.authorLewiński, Krzysztof - 129948 pl
dc.contributor.authorGillaizeau, Isabellepl
dc.date.accessioned2015-08-24T07:16:58Z
dc.date.available2015-08-24T07:16:58Z
dc.date.issued2012pl
dc.description.additionalNa publikacji autorka Cieślikiewicz-Bouet Monika podpisana jako Cieślikiewicz Monika.pl
dc.description.number6pl
dc.description.physical1101-1106pl
dc.description.points30pl
dc.description.volume2012pl
dc.identifier.doi10.1002/ejoc.201101293pl
dc.identifier.eissn1099-0690pl
dc.identifier.issn1434-193Xpl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/14848
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licencebez licencji
dc.rights.uri*
dc.subject.encross-couplingpl
dc.subject.enenolspl
dc.subject.enphosphaalkenespl
dc.subject.enphosphanespl
dc.subject.enboranespl
dc.subtypeArticlepl
dc.titleP-C cross-coupling onto enamides : versatile synthesis of $\alpha$-enamido phosphane derivativespl
dc.title.journalEuropean Journal of Organic Chemistrypl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-10T00:23:03Z
dc.abstract.enpl
We report herein the Pd-catalyzed P-C cross-coupling reac- tion between enol phosphates and secondary phosphane–bor- ane complexes or phosphane oxides. The reaction was per- formed under mild conditions, owing to Pd activation of the P-H bonds of the phosphane–boranes (or phosphane oxides) and to the powerful enol phosphate coupling reagents. New useful chiral and achiral $\alpha$-$\beta$-alkenylphosphane derivatives bearing an amido group in the $\alpha$-position to the P center were obtained in yields up to 70 %.
dc.affiliationpl
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki
dc.contributor.authorpl
Cieślikiewicz-Bouet, Monika - 126193
dc.contributor.authorpl
Bouet, Alexis
dc.contributor.authorpl
Jugé, Sylvain
dc.contributor.authorpl
Toffano, Martial
dc.contributor.authorpl
Bayardon, Jérôme
dc.contributor.authorpl
West, Caroline
dc.contributor.authorpl
Lewiński, Krzysztof - 129948
dc.contributor.authorpl
Gillaizeau, Isabelle
dc.date.accessioned
2015-08-24T07:16:58Z
dc.date.available
2015-08-24T07:16:58Z
dc.date.issuedpl
2012
dc.description.additionalpl
Na publikacji autorka Cieślikiewicz-Bouet Monika podpisana jako Cieślikiewicz Monika.
dc.description.numberpl
6
dc.description.physicalpl
1101-1106
dc.description.pointspl
30
dc.description.volumepl
2012
dc.identifier.doipl
10.1002/ejoc.201101293
dc.identifier.eissnpl
1099-0690
dc.identifier.issnpl
1434-193X
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/14848
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
bez licencji
dc.rights.uri*
dc.subject.enpl
cross-coupling
dc.subject.enpl
enols
dc.subject.enpl
phosphaalkenes
dc.subject.enpl
phosphanes
dc.subject.enpl
boranes
dc.subtypepl
Article
dc.titlepl
P-C cross-coupling onto enamides : versatile synthesis of $\alpha$-enamido phosphane derivatives
dc.title.journalpl
European Journal of Organic Chemistry
dc.typepl
JournalArticle
dspace.entity.type
Publication

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