Metal-to-metal electron-transfer emission in cyanide-bridged chromium : ruthenium complexes : effects of configurational mixing between ligand field and charge transfer excited states

2008
journal article
article
20
dc.abstract.enIrradiations of the transition metal-to-transition metal charge transfer (MMCT) absorption bands of a series of cyanide-bridged chromium(III)-ruthenium(II) complexes at 77 K leads to near-infrared emission spectra of the corresponding chromium(II)-ruthenium(III) electron transfer excited states. The lifetimes of most of the MMCT excited states increase more than 10-fold when their am(m)ine ligands are perdueterated. These unique emissions have weak, low frequency vibronic sidebands that correspond to the small excited-state distortions in metal-ligand bonds that are characteristic of transition metal electron transfer involving only the non-bonding metal centered d-orbitals suggesting that the excited-state Cr(II) center has a triplet spin configuration. However, most of the electronically excited complexes probably have overall doublet spin multiplicity and exhibit an excitation energy dependent dual emission with the near in energy Cr(III)-centered and MMCT doublet excited states forming an unusual mixed valence pair.pl
dc.contributor.authorChen, Yuan-Jangpl
dc.contributor.authorOdongo, Onduru S.pl
dc.contributor.authorMcNamara, Patrick G.pl
dc.contributor.authorSzaciłowski, Konrad - 132185 pl
dc.contributor.authorEndicott, John F.pl
dc.date.accessioned2015-08-21T12:17:31Z
dc.date.available2015-08-21T12:17:31Z
dc.date.issued2008pl
dc.description.number23pl
dc.description.physical10921-10934pl
dc.description.volume47pl
dc.identifier.doi10.1021/ic8011266pl
dc.identifier.eissn1520-510Xpl
dc.identifier.issn0020-1669pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/14830
dc.languageengpl
dc.language.containerengpl
dc.subtypeArticlepl
dc.titleMetal-to-metal electron-transfer emission in cyanide-bridged chromium : ruthenium complexes : effects of configurational mixing between ligand field and charge transfer excited statespl
dc.title.journalInorganic Chemistrypl
dc.typeJournalArticlepl
dspace.entity.typePublication
dc.abstract.enpl
Irradiations of the transition metal-to-transition metal charge transfer (MMCT) absorption bands of a series of cyanide-bridged chromium(III)-ruthenium(II) complexes at 77 K leads to near-infrared emission spectra of the corresponding chromium(II)-ruthenium(III) electron transfer excited states. The lifetimes of most of the MMCT excited states increase more than 10-fold when their am(m)ine ligands are perdueterated. These unique emissions have weak, low frequency vibronic sidebands that correspond to the small excited-state distortions in metal-ligand bonds that are characteristic of transition metal electron transfer involving only the non-bonding metal centered d-orbitals suggesting that the excited-state Cr(II) center has a triplet spin configuration. However, most of the electronically excited complexes probably have overall doublet spin multiplicity and exhibit an excitation energy dependent dual emission with the near in energy Cr(III)-centered and MMCT doublet excited states forming an unusual mixed valence pair.
dc.contributor.authorpl
Chen, Yuan-Jang
dc.contributor.authorpl
Odongo, Onduru S.
dc.contributor.authorpl
McNamara, Patrick G.
dc.contributor.authorpl
Szaciłowski, Konrad - 132185
dc.contributor.authorpl
Endicott, John F.
dc.date.accessioned
2015-08-21T12:17:31Z
dc.date.available
2015-08-21T12:17:31Z
dc.date.issuedpl
2008
dc.description.numberpl
23
dc.description.physicalpl
10921-10934
dc.description.volumepl
47
dc.identifier.doipl
10.1021/ic8011266
dc.identifier.eissnpl
1520-510X
dc.identifier.issnpl
0020-1669
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/14830
dc.languagepl
eng
dc.language.containerpl
eng
dc.subtypepl
Article
dc.titlepl
Metal-to-metal electron-transfer emission in cyanide-bridged chromium : ruthenium complexes : effects of configurational mixing between ligand field and charge transfer excited states
dc.title.journalpl
Inorganic Chemistry
dc.typepl
JournalArticle
dspace.entity.type
Publication
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