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Stability of ion triplets in ionic liquid/lithium salt solutions : insights from implicit and explicit solvent models and molecular dynamics simulations
ionic liquids
explicit solvent model
ion aggregates
continuous solvent
Binding energies of ion triplets formed in ionic liquids by Li+ with two anions have been studied using quantum-chemical calculations with implicit and explicit solvent supplemented by molecular dynamics (MD) simulations. Explicit solvent approach confirms variation of solute-ionic liquid interactions at distances up to 2 nm, resulting from structure of solvation shells induced by electric field of the solute. Binding energies computed in explicit solvent and from the polarizable continuum model approach differ largely, even in sign, but relative values generally agree between these two models. Stabilities of ion triplets obtained in quantum-chemical calculations for some systems disagree with MD results; the discrepancy is attributed to the difference between static optimized geometries used in quantum chemical modeling and dynamic structures of triplets in MD simulations
cris.lastimport.scopus | 2024-04-27T01:25:14Z | |
dc.abstract.en | Binding energies of ion triplets formed in ionic liquids by Li+ with two anions have been studied using quantum-chemical calculations with implicit and explicit solvent supplemented by molecular dynamics (MD) simulations. Explicit solvent approach confirms variation of solute-ionic liquid interactions at distances up to 2 nm, resulting from structure of solvation shells induced by electric field of the solute. Binding energies computed in explicit solvent and from the polarizable continuum model approach differ largely, even in sign, but relative values generally agree between these two models. Stabilities of ion triplets obtained in quantum-chemical calculations for some systems disagree with MD results; the discrepancy is attributed to the difference between static optimized geometries used in quantum chemical modeling and dynamic structures of triplets in MD simulations | pl |
dc.affiliation | Wydział Chemii : Zakład Metod Obliczeniowych Chemii | pl |
dc.contributor.author | Eilmes, Andrzej - 127871 | pl |
dc.contributor.author | Kubisiak, Piotr - 126382 | pl |
dc.date.accessioned | 2015-07-03T16:27:34Z | |
dc.date.available | 2015-07-03T16:27:34Z | |
dc.date.issued | 2015 | pl |
dc.description.number | 10 | pl |
dc.description.physical | 751-762 | pl |
dc.description.volume | 36 | pl |
dc.identifier.doi | 10.1002/jcc.23853 | pl |
dc.identifier.eissn | 1096-987X | pl |
dc.identifier.issn | 0192-8651 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/11516 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights.licence | bez licencji | |
dc.subject.en | ionic liquids | pl |
dc.subject.en | explicit solvent model | pl |
dc.subject.en | ion aggregates | pl |
dc.subject.en | continuous solvent | pl |
dc.subtype | Article | pl |
dc.title | Stability of ion triplets in ionic liquid/lithium salt solutions : insights from implicit and explicit solvent models and molecular dynamics simulations | pl |
dc.title.journal | Journal of Computational Chemistry | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |