Red analytical performance index (RAPI) and software : the missing tool for assessing methods in terms of analytical performance

2025
journal article
article
dc.abstract.enAlthough performing validation of an analytical method is a widely accepted standard, assessing and comparing the overall analytical potential covering all validation criteria is not straightforward. To answer the expectations of analytical chemists, we propose a new tool that solves this problem in a simple and user-friendly way. The Red Analytical Performance Index (RAPI) presented in this article is inspired by the Red-Green-Blue assessment model, in which the red colour represents analytical criteria. A simple, open-source software (mostwiedzy.pl/rapi) is used to assess the given method in relation to the ten pre-defined criteria. The performance in particular criteria is scored (0, 2.5, 5.0, 7.5, or 10 points), with the sores mapped to colour intensity and saturation where 0 is white and 10 is dark red. A star-like pictogram is automatically created, and divided into fields related to the particular criteria, with the final, mean quantitative assessment score (0–100) in the middle. It thus shows similarities to the Blue Applicability Grade Index (BAGI) – a recently published “sister” tool dedicated to practical criteria represented by the blue colour. Therefore, RAPI and BAGI can support and supplement known greenness assessment metrics, providing key information about functional characteristics, crucial for the method application. The use of RAPI was demonstrated using examples of various analytical methods, which were assessed in parallel using BAGI and the greenness metrics showing the closest analogy. This provided a comprehensive picture of the varied methods’ characteristics. We believe that RAPI will prove to be an effective and useful support for analytical chemists in methods evaluation and comparison.
dc.affiliationWydział Chemii : Zakład Chemii Analitycznej
dc.contributor.authorNowak, Paweł - 149463
dc.contributor.authorWojnowski, Wojciech
dc.contributor.authorManousi, Natalia
dc.contributor.authorSamanidou, Victoria
dc.contributor.authorPłotka-Wasylka, Justyna
dc.date.accession2025-05-26
dc.date.accessioned2025-05-26T11:37:17Z
dc.date.available2025-05-26T11:37:17Z
dc.date.createdat2025-05-23T08:37:53Zen
dc.date.issued2025
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number19
dc.description.physical5546-5553
dc.description.versionostateczna wersja wydawcy
dc.description.volume27
dc.identifier.doi10.1039/D4GC05298F
dc.identifier.eissn1463-9270
dc.identifier.issn1463-9262
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/552781
dc.identifier.weblinkhttps://pubs.rsc.org/en/content/articlehtml/2025/gc/d4gc05298f
dc.languageeng
dc.language.containereng
dc.rightsDodaję tylko opis bibliograficzny
dc.rights.licenceCC-BY-NC
dc.share.typeinne
dc.subtypeArticle
dc.titleRed analytical performance index (RAPI) and software : the missing tool for assessing methods in terms of analytical performance
dc.title.journalGreen Chemistry
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
Although performing validation of an analytical method is a widely accepted standard, assessing and comparing the overall analytical potential covering all validation criteria is not straightforward. To answer the expectations of analytical chemists, we propose a new tool that solves this problem in a simple and user-friendly way. The Red Analytical Performance Index (RAPI) presented in this article is inspired by the Red-Green-Blue assessment model, in which the red colour represents analytical criteria. A simple, open-source software (mostwiedzy.pl/rapi) is used to assess the given method in relation to the ten pre-defined criteria. The performance in particular criteria is scored (0, 2.5, 5.0, 7.5, or 10 points), with the sores mapped to colour intensity and saturation where 0 is white and 10 is dark red. A star-like pictogram is automatically created, and divided into fields related to the particular criteria, with the final, mean quantitative assessment score (0–100) in the middle. It thus shows similarities to the Blue Applicability Grade Index (BAGI) – a recently published “sister” tool dedicated to practical criteria represented by the blue colour. Therefore, RAPI and BAGI can support and supplement known greenness assessment metrics, providing key information about functional characteristics, crucial for the method application. The use of RAPI was demonstrated using examples of various analytical methods, which were assessed in parallel using BAGI and the greenness metrics showing the closest analogy. This provided a comprehensive picture of the varied methods’ characteristics. We believe that RAPI will prove to be an effective and useful support for analytical chemists in methods evaluation and comparison.
dc.affiliation
Wydział Chemii : Zakład Chemii Analitycznej
dc.contributor.author
Nowak, Paweł - 149463
dc.contributor.author
Wojnowski, Wojciech
dc.contributor.author
Manousi, Natalia
dc.contributor.author
Samanidou, Victoria
dc.contributor.author
Płotka-Wasylka, Justyna
dc.date.accession
2025-05-26
dc.date.accessioned
2025-05-26T11:37:17Z
dc.date.available
2025-05-26T11:37:17Z
dc.date.createdaten
2025-05-23T08:37:53Z
dc.date.issued
2025
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.number
19
dc.description.physical
5546-5553
dc.description.version
ostateczna wersja wydawcy
dc.description.volume
27
dc.identifier.doi
10.1039/D4GC05298F
dc.identifier.eissn
1463-9270
dc.identifier.issn
1463-9262
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/552781
dc.identifier.weblink
https://pubs.rsc.org/en/content/articlehtml/2025/gc/d4gc05298f
dc.language
eng
dc.language.container
eng
dc.rights
Dodaję tylko opis bibliograficzny
dc.rights.licence
CC-BY-NC
dc.share.type
inne
dc.subtype
Article
dc.title
Red analytical performance index (RAPI) and software : the missing tool for assessing methods in terms of analytical performance
dc.title.journal
Green Chemistry
dc.type
JournalArticle
dspace.entity.typeen
Publication
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