Spectroscopic techniques in the investigation of extraordinary medieval Polish coins : revealing the presence of hidden cores

2025
journal article
article
dc.abstract.enCross denars, frequently found in Polish hoards, were traditionally thought to be Ag coins with some Cu content. This study investigates the possibility of a hidden Cu core beneath the Ag or Ag-Cu surface of these coins. It raises questions about whether they were counterfeits or intentionally designed for mass production. Unlike Roman denarii, which revealed their cores when broken, the examination of cross denars without damage is challenging. Optical microscopy and microanalysis revealed differences in the composition of early medieval Polish coins, challenging the belief that cross denars were homogeneous Ag-Cu alloys. Detailed spectroscopic analyses, including energy-dispersive X-ray fluorescence (ED-XRF), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), micro X-ray fluorescence (μXRF), and microparticle-induced X-ray emission (μ-PIXE) measurements, were conducted. These analyses of two cross denars uncovered one composed of an Ag-Cu alloy and another manufactured by plating a Cu-Zn core with an Ag sheet. This suggests the need for further research in the history and technology of minting in Poland in the Early Middle Ages. It also prompts a reconsideration of the applicability of noninvasive X-ray techniques for archaeological examinations.
dc.contributor.authorTrela, Krystian
dc.contributor.authorGójska, Aneta Maria
dc.contributor.authorMiśta-Jakubowska, Ewelina - 495287
dc.contributor.authorKelemen, Mitja
dc.contributor.authorŠmit, Žiga
dc.contributor.authorKędzierski, Adam
dc.contributor.authorGarbacz-Klempka, Aldona
dc.date.accessioned2025-03-11T10:07:17Z
dc.date.available2025-03-11T10:07:17Z
dc.date.createdat2025-02-12T17:22:30Zen
dc.date.issued2025
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number1
dc.description.physical19-27
dc.description.versionostateczna wersja wydawcy
dc.description.volume70
dc.identifier.doi10.2478/nuka-2025-0003
dc.identifier.eissn1508-5791
dc.identifier.issn0029-5922
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/550058
dc.languageeng
dc.language.containereng
dc.rightsUdzielam licencji. Uznanie autorstwa - Użycie niekomercyjne - Bez utworów zależnych 4.0 Międzynarodowa
dc.rights.licenceCC-BY-NC-ND
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.pl
dc.share.typeotwarte repozytorium
dc.subject.enAg medieval coins
dc.subject.encore coins
dc.subject.enED-XRF
dc.subject.enmicroanalyses
dc.subject.enPIXE
dc.subject.enSEM-EDS
dc.subtypeArticle
dc.titleSpectroscopic techniques in the investigation of extraordinary medieval Polish coins : revealing the presence of hidden cores
dc.title.journalNukleonika
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
Cross denars, frequently found in Polish hoards, were traditionally thought to be Ag coins with some Cu content. This study investigates the possibility of a hidden Cu core beneath the Ag or Ag-Cu surface of these coins. It raises questions about whether they were counterfeits or intentionally designed for mass production. Unlike Roman denarii, which revealed their cores when broken, the examination of cross denars without damage is challenging. Optical microscopy and microanalysis revealed differences in the composition of early medieval Polish coins, challenging the belief that cross denars were homogeneous Ag-Cu alloys. Detailed spectroscopic analyses, including energy-dispersive X-ray fluorescence (ED-XRF), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), micro X-ray fluorescence (μXRF), and microparticle-induced X-ray emission (μ-PIXE) measurements, were conducted. These analyses of two cross denars uncovered one composed of an Ag-Cu alloy and another manufactured by plating a Cu-Zn core with an Ag sheet. This suggests the need for further research in the history and technology of minting in Poland in the Early Middle Ages. It also prompts a reconsideration of the applicability of noninvasive X-ray techniques for archaeological examinations.
dc.contributor.author
Trela, Krystian
dc.contributor.author
Gójska, Aneta Maria
dc.contributor.author
Miśta-Jakubowska, Ewelina - 495287
dc.contributor.author
Kelemen, Mitja
dc.contributor.author
Šmit, Žiga
dc.contributor.author
Kędzierski, Adam
dc.contributor.author
Garbacz-Klempka, Aldona
dc.date.accessioned
2025-03-11T10:07:17Z
dc.date.available
2025-03-11T10:07:17Z
dc.date.createdaten
2025-02-12T17:22:30Z
dc.date.issued
2025
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.number
1
dc.description.physical
19-27
dc.description.version
ostateczna wersja wydawcy
dc.description.volume
70
dc.identifier.doi
10.2478/nuka-2025-0003
dc.identifier.eissn
1508-5791
dc.identifier.issn
0029-5922
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/550058
dc.language
eng
dc.language.container
eng
dc.rights
Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne - Bez utworów zależnych 4.0 Międzynarodowa
dc.rights.licence
CC-BY-NC-ND
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.pl
dc.share.type
otwarte repozytorium
dc.subject.en
Ag medieval coins
dc.subject.en
core coins
dc.subject.en
ED-XRF
dc.subject.en
microanalyses
dc.subject.en
PIXE
dc.subject.en
SEM-EDS
dc.subtype
Article
dc.title
Spectroscopic techniques in the investigation of extraordinary medieval Polish coins : revealing the presence of hidden cores
dc.title.journal
Nukleonika
dc.type
JournalArticle
dspace.entity.typeen
Publication
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