Stability of biaxial nematic phase for systems with variable molecular shape anisotropy

2007
journal article
article
23
cris.lastimport.wos2024-04-09T23:34:13Z
dc.abstract.enWe study the influence of fluctuations in molecular shape on the stability of the biaxial nematic phase by generalizing the mean-field model of Mulder and Ruijgrok [Physica A 113, 145 (1982)]. We limit ourselves to the case when the molecular shape anisotropy, represented by the alignment tensor, is a random variable of an annealed type. A prototype of such behavior can be found in lyotropic systems—a mixture of potassium laurate, 1-decanol, and D_{2}O, where distribution of the micellar shape adjusts to actual equilibrium conditions. Further examples of materials with the biaxial nematic phase, where molecular shape is subject to fluctuations, are thermotropic materials composed of flexible trimericlike or tetrapodlike molecular units. Our calculations show that the Gaussian equilibrium distribution of the variables describing molecular shape (dispersion force) anisotropy gives rise to new classes of the phase diagrams, absent in the original model. Depending on properties of the shape fluctuations, the stability of the biaxial nematic phase can be either enhanced or depressed, relative to the uniaxial nematic phases. In the former case the splitting of the Landau point into two triple points with a direct phase transition line from isotropic to biaxial phase is observed.pl
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiegopl
dc.contributor.authorLonga, Lech - 100154 pl
dc.contributor.authorPająk, Grzegorz - 200615 pl
dc.contributor.authorWydro, Thomaspl
dc.date.accessioned2017-07-25T11:16:25Z
dc.date.available2017-07-25T11:16:25Z
dc.date.issued2007pl
dc.description.number1pl
dc.description.volume76pl
dc.identifier.articleid011703pl
dc.identifier.doi10.1103/PhysRevE.76.011703pl
dc.identifier.eissn1550-2376pl
dc.identifier.issn1539-3755pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/42974
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licenceBez licencji otwartego dostępu
dc.source.integratorfalse
dc.subtypeArticlepl
dc.titleStability of biaxial nematic phase for systems with variable molecular shape anisotropypl
dc.title.journalPhysical Review. E, Statistical, Nonlinear, and Soft Matter Physicspl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T23:34:13Z
dc.abstract.enpl
We study the influence of fluctuations in molecular shape on the stability of the biaxial nematic phase by generalizing the mean-field model of Mulder and Ruijgrok [Physica A 113, 145 (1982)]. We limit ourselves to the case when the molecular shape anisotropy, represented by the alignment tensor, is a random variable of an annealed type. A prototype of such behavior can be found in lyotropic systems—a mixture of potassium laurate, 1-decanol, and D_{2}O, where distribution of the micellar shape adjusts to actual equilibrium conditions. Further examples of materials with the biaxial nematic phase, where molecular shape is subject to fluctuations, are thermotropic materials composed of flexible trimericlike or tetrapodlike molecular units. Our calculations show that the Gaussian equilibrium distribution of the variables describing molecular shape (dispersion force) anisotropy gives rise to new classes of the phase diagrams, absent in the original model. Depending on properties of the shape fluctuations, the stability of the biaxial nematic phase can be either enhanced or depressed, relative to the uniaxial nematic phases. In the former case the splitting of the Landau point into two triple points with a direct phase transition line from isotropic to biaxial phase is observed.
dc.affiliationpl
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorpl
Longa, Lech - 100154
dc.contributor.authorpl
Pająk, Grzegorz - 200615
dc.contributor.authorpl
Wydro, Thomas
dc.date.accessioned
2017-07-25T11:16:25Z
dc.date.available
2017-07-25T11:16:25Z
dc.date.issuedpl
2007
dc.description.numberpl
1
dc.description.volumepl
76
dc.identifier.articleidpl
011703
dc.identifier.doipl
10.1103/PhysRevE.76.011703
dc.identifier.eissnpl
1550-2376
dc.identifier.issnpl
1539-3755
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/42974
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
Bez licencji otwartego dostępu
dc.source.integrator
false
dc.subtypepl
Article
dc.titlepl
Stability of biaxial nematic phase for systems with variable molecular shape anisotropy
dc.title.journalpl
Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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