Synthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogs

2014
journal article
article
cris.lastimport.wos2024-04-09T21:32:13Z
dc.abstract.enA series of W(IV) complexes with 2-aminoethanol and 5-bromo-, 5-chloro-, 5-methoxy-, 3,5 -dichloro- substituted salicylaldehydes is described. The complexes were isolated and characterized by elemental analysis, IR and UV–Vis spectroscopy as well as cyclic voltammetry. The single crystal X-ray analysis of salt (PPh 4 ) 2 [W(CN) 3 O(metsal)] 5H 2 O (where metsal = Schiff bases formed in situ in the reaction of ami- noethanol and 5-methoxysalicylaldehyde) indicate a distorted octahedral geometry of the anions with Hmetsal as N,O-donating ligand. The isolated salts of W(IV) are compared to Mo(IV) analogs.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorTomecka-Wątroba, Monika - 167723 pl
dc.contributor.authorSzklarzewicz, Janusz - 132237 pl
dc.contributor.authorJurowska, Anna - 163745 pl
dc.contributor.authorWojtczak, Andrzejpl
dc.date.accessioned2015-06-22T11:24:35Z
dc.date.available2015-06-22T11:24:35Z
dc.date.issued2014pl
dc.description.additionalNa publikacji autorka Tomecka-Wątroba Monika podpisana jako Tomecka Monika.pl
dc.description.physical81-89pl
dc.description.volume81pl
dc.identifier.doi10.1016/j.poly.2014.05.064pl
dc.identifier.eissn1873-3719pl
dc.identifier.issn0277-5387pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/9960
dc.languageengpl
dc.language.containerengpl
dc.rights.licencebez licencji
dc.subject.entungstenpl
dc.subject.ensalicylaldehydepl
dc.subject.enschiff basespl
dc.subject.enX-ray structurepl
dc.subject.encomplexespl
dc.subtypeArticlepl
dc.titleSynthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogspl
dc.title.journalPolyhedronpl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T21:32:13Z
dc.abstract.enpl
A series of W(IV) complexes with 2-aminoethanol and 5-bromo-, 5-chloro-, 5-methoxy-, 3,5 -dichloro- substituted salicylaldehydes is described. The complexes were isolated and characterized by elemental analysis, IR and UV–Vis spectroscopy as well as cyclic voltammetry. The single crystal X-ray analysis of salt (PPh 4 ) 2 [W(CN) 3 O(metsal)] 5H 2 O (where metsal = Schiff bases formed in situ in the reaction of ami- noethanol and 5-methoxysalicylaldehyde) indicate a distorted octahedral geometry of the anions with Hmetsal as N,O-donating ligand. The isolated salts of W(IV) are compared to Mo(IV) analogs.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.authorpl
Tomecka-Wątroba, Monika - 167723
dc.contributor.authorpl
Szklarzewicz, Janusz - 132237
dc.contributor.authorpl
Jurowska, Anna - 163745
dc.contributor.authorpl
Wojtczak, Andrzej
dc.date.accessioned
2015-06-22T11:24:35Z
dc.date.available
2015-06-22T11:24:35Z
dc.date.issuedpl
2014
dc.description.additionalpl
Na publikacji autorka Tomecka-Wątroba Monika podpisana jako Tomecka Monika.
dc.description.physicalpl
81-89
dc.description.volumepl
81
dc.identifier.doipl
10.1016/j.poly.2014.05.064
dc.identifier.eissnpl
1873-3719
dc.identifier.issnpl
0277-5387
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9960
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights.licence
bez licencji
dc.subject.enpl
tungsten
dc.subject.enpl
salicylaldehyde
dc.subject.enpl
schiff bases
dc.subject.enpl
X-ray structure
dc.subject.enpl
complexes
dc.subtypepl
Article
dc.titlepl
Synthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogs
dc.title.journalpl
Polyhedron
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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