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Synthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogs
Journal
Polyhedron
Author
Tomecka-Wątroba Monika
Szklarzewicz Janusz
Jurowska Anna
Wojtczak Andrzej
Volume
81
Pages
81-89
ISSN
0277-5387
eISSN
1873-3719
Keywords in English
tungsten
salicylaldehyde
schiff bases
X-ray structure
complexes
Remarks
Na publikacji autorka Tomecka-Wątroba Monika podpisana jako Tomecka Monika.
Language
English
Journal language
English
Abstract in English
A series of W(IV) complexes with 2-aminoethanol and 5-bromo-, 5-chloro-, 5-methoxy-, 3,5 -dichloro- substituted salicylaldehydes is described. The complexes were isolated and characterized by elemental analysis, IR and UV–Vis spectroscopy as well as cyclic voltammetry. The single crystal X-ray analysis of salt (PPh 4 ) 2 [W(CN) 3 O(metsal)]
5H 2 O (where metsal = Schiff bases formed in situ in the reaction of ami- noethanol and 5-methoxysalicylaldehyde) indicate a distorted octahedral geometry of the anions with Hmetsal as N,O-donating ligand. The isolated salts of W(IV) are compared to Mo(IV) analogs.
Affiliation
Wydział Chemii : Zakład Chemii Nieorganicznej
Scopus© citations
3
| cris.lastimport.wos | 2024-04-09T21:32:13Z | |
| dc.abstract.en | A series of W(IV) complexes with 2-aminoethanol and 5-bromo-, 5-chloro-, 5-methoxy-, 3,5 -dichloro- substituted salicylaldehydes is described. The complexes were isolated and characterized by elemental analysis, IR and UV–Vis spectroscopy as well as cyclic voltammetry. The single crystal X-ray analysis of salt (PPh 4 ) 2 [W(CN) 3 O(metsal)] 5H 2 O (where metsal = Schiff bases formed in situ in the reaction of ami- noethanol and 5-methoxysalicylaldehyde) indicate a distorted octahedral geometry of the anions with Hmetsal as N,O-donating ligand. The isolated salts of W(IV) are compared to Mo(IV) analogs. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.contributor.author | Tomecka-Wątroba, Monika - 167723 | pl |
| dc.contributor.author | Szklarzewicz, Janusz - 132237 | pl |
| dc.contributor.author | Jurowska, Anna - 163745 | pl |
| dc.contributor.author | Wojtczak, Andrzej | pl |
| dc.date.accessioned | 2015-06-22T11:24:35Z | |
| dc.date.available | 2015-06-22T11:24:35Z | |
| dc.date.issued | 2014 | pl |
| dc.description.additional | Na publikacji autorka Tomecka-Wątroba Monika podpisana jako Tomecka Monika. | pl |
| dc.description.physical | 81-89 | pl |
| dc.description.volume | 81 | pl |
| dc.identifier.doi | 10.1016/j.poly.2014.05.064 | pl |
| dc.identifier.eissn | 1873-3719 | pl |
| dc.identifier.issn | 0277-5387 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9960 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights.licence | Bez licencji otwartego dostępu | |
| dc.subject.en | tungsten | pl |
| dc.subject.en | salicylaldehyde | pl |
| dc.subject.en | schiff bases | pl |
| dc.subject.en | X-ray structure | pl |
| dc.subject.en | complexes | pl |
| dc.subtype | Article | pl |
| dc.title | Synthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogs | pl |
| dc.title.journal | Polyhedron | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
cris.lastimport.wos
2024-04-09T21:32:13Z dc.abstract.enpl
A series of W(IV) complexes with 2-aminoethanol and 5-bromo-, 5-chloro-, 5-methoxy-, 3,5 -dichloro-
substituted salicylaldehydes is described. The complexes were isolated and characterized by elemental
analysis, IR and UV–Vis spectroscopy as well as cyclic voltammetry. The single crystal X-ray analysis
of salt (PPh
4
)
2
[W(CN)
3
O(metsal)]
5H
2
O (where metsal = Schiff bases formed in situ in the reaction of ami-
noethanol and 5-methoxysalicylaldehyde) indicate a distorted octahedral geometry of the anions with
Hmetsal as N,O-donating ligand. The isolated salts of W(IV) are compared to Mo(IV) analogs. dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej dc.contributor.authorpl
Tomecka-Wątroba, Monika - 167723 dc.contributor.authorpl
Szklarzewicz, Janusz - 132237 dc.contributor.authorpl
Jurowska, Anna - 163745 dc.contributor.authorpl
Wojtczak, Andrzej dc.date.accessioned
2015-06-22T11:24:35Z dc.date.available
2015-06-22T11:24:35Z dc.date.issuedpl
2014 dc.description.additionalpl
Na publikacji autorka Tomecka-Wątroba Monika podpisana jako Tomecka Monika. dc.description.physicalpl
81-89 dc.description.volumepl
81 dc.identifier.doipl
10.1016/j.poly.2014.05.064 dc.identifier.eissnpl
1873-3719 dc.identifier.issnpl
0277-5387 dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9960 dc.languagepl
eng dc.language.containerpl
eng dc.rights.licence
Bez licencji otwartego dostępu dc.subject.enpl
tungsten dc.subject.enpl
salicylaldehyde dc.subject.enpl
schiff bases dc.subject.enpl
X-ray structure dc.subject.enpl
complexes dc.subtypepl
Article dc.titlepl
Synthesis, structure and properties of oxocyanido W(IV) complexes with substituted salicylaldimines of 2-aminoethanol compared to Mo(IV) analogs dc.title.journalpl
Polyhedron dc.typepl
JournalArticle dspace.entity.type
Publication Affiliations
Wydział Chemii
Szklarzewicz, Janusz
Jurowska, Anna
Tomecka-Wątroba, Monika
No affiliation
Wojtczak, Andrzej
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