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Catalytic performance of sucrose-derived CMK-3 in oxidative dehydrogenation of propane to propene
oxidative dehydrogenation
carbon replica
propene
CMK-3
Na publikacji autorka Janus Paula podpisana jako Niebrzydowska Paula.
CMK-3
carbon
replica
was
synthesized
by
carbonization
of
sucrose
introduced
to
the
pore
system
of
a
SBA-
15
hard
template
followed
by
dissolving
with
HF.
The
material
with
a
stable
hexagonal
structure
and
an
expanded
surface
area
was
obtained.
TG
measurements
showed
that
CMK-3
type
mesoporous
carbon
started
to
be
intensively
oxidized
by
molecular
above
723
K.
This
carbon
sample
was
tested
as
a
catalyst
of
dehydrogenation
of
propane
to
propene
under
oxidative
( =0.25,
0.50
and
1.00)
and
non-oxidative
(O
2
:C
3
H
8
0.00)
conditions
in
the
temperature
range
from
573
to
873
K.
The
propene
yield
increased
with
rise
in
the
reaction
temperature,
however
above
573
K
the
formation
of
side-
products
(
| cris.lastimport.wos | 2024-04-10T00:22:13Z | |
| dc.abstract.en | CMK-3 carbon replica was synthesized by carbonization of sucrose introduced to the pore system of a SBA- 15 hard template followed by dissolving $SiO_{2}$ with HF. The material with a stable hexagonal structure and an expanded surface area $(S_{BET}=1287m^{2}/g)$ was obtained. TG measurements showed that CMK-3 type mesoporous carbon started to be intensively oxidized by molecular $O_{2}$ above 723 K. This carbon sample was tested as a catalyst of dehydrogenation of propane to propene under oxidative ($O_{2}:C_{3}H_{8}$=0.25, 0.50 and 1.00) and non-oxidative (O 2 :C 3 H 8 = 0.00) conditions in the temperature range from 573 to 873 K. The propene yield increased with rise in the reaction temperature, however above 573 K the formation of side- products ($C_{2}H_{6}, C_{2}H_{4}, CH_{4}$ and $H_{2}$) was observed. Moreover, coke was deposited on the catalyst surface. A decrease in the mass of a catalyst bed after the catalytic runs suggested the participation of oxygen in burning of deposited and bulk coke. The surface composition of a spent catalyst was investigated by XPS and TPD analysis. The changes in the concentration of oxygen functional groups, caused by the catalytic reaction, were observed regardless of a reaction temperature and feed composition. | pl |
| dc.affiliation | Wydział Chemii : Zakład Technologii Chemicznej | pl |
| dc.contributor.author | Michorczyk, Piotr | pl |
| dc.contributor.author | Kuśtrowski, Piotr - 129800 | pl |
| dc.contributor.author | Janus, Paula - 112931 | pl |
| dc.contributor.author | Wach, Anna - 126105 | pl |
| dc.date.accessioned | 2015-09-03T09:20:28Z | |
| dc.date.available | 2015-09-03T09:20:28Z | |
| dc.date.issued | 2012 | pl |
| dc.description.additional | Na publikacji autorka Janus Paula podpisana jako Niebrzydowska Paula. | pl |
| dc.description.physical | 321-328 | pl |
| dc.description.points | 35 | pl |
| dc.description.volume | 445-446 | pl |
| dc.identifier.doi | 10.1016/j.apcata.2012.08.044 | pl |
| dc.identifier.eissn | 1873-3875 | pl |
| dc.identifier.issn | 0926-860X | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/15317 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights | Dodaję tylko opis bibliograficzny | * |
| dc.rights.licence | Bez licencji otwartego dostępu | |
| dc.source.integrator | false | |
| dc.subject.en | oxidative dehydrogenation | pl |
| dc.subject.en | carbon replica | pl |
| dc.subject.en | propene | pl |
| dc.subject.en | CMK-3 | pl |
| dc.subtype | Article | pl |
| dc.title | Catalytic performance of sucrose-derived CMK-3 in oxidative dehydrogenation of propane to propene | pl |
| dc.title.journal | Applied Catalysis. A, General | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |