Real-world application of molecularly imprinted -graphite photocatalysts : efficient pharmaceutical removal under energy-optimized LED system

2025
journal article
article
2
dc.abstract.enThis study introduces a novel approach to the selective degradation of pharmaceuticals in wastewater using a molecularly imprinted $TiO_{2}$-recycled graphite photocatalyst. The photocatalyst was synthesized through a rapid microwave-assisted method, incorporating recycled graphite from spent lithium-ion batteries and imprinting metronidazole (MNZ) as a template molecule. The addition of graphite improved charge separation and extended the excitation range of the photocatalyst, which was effectively utilized by a tailored LED light source. The system was tested in diverse wastewater environments, including primary sewage and hospital effluent, to assess its efficacy and selectivity. Photocatalytic degradation tests revealed that the molecularly imprinted photocatalyst (MIP) achieved over 60 % MNZ degradation in primary sewage within 60 min, significantly reducing the risk of pharmaceutical transfer to the biological stage of wastewater treatment. The photocatalyst exhibited excellent stability over multiple catalytic cycles, maintaining high performance with only minor decreases in efficiency. Furthermore, tests conducted on hospital wastewater confirmed the high selectivity of the MIP photocatalysts, achieving over 75 % MNZ degradation, showcasing their robustness in real-world, complex wastewater matrices. These results underscore the stability, selectivity, and superior performance of MIP-based $TiO_{2}-G$ photocatalysts, offering a sustainable and efficient solution for pharmaceutical removal in wastewater treatment applications.
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.authorKubiak, Adam
dc.contributor.authorJaruga, Marta
dc.contributor.authorLusina, Aleksandra
dc.contributor.authorNazim, Tomasz
dc.contributor.authorSobańska, Kamila - 155916
dc.contributor.authorPietrzyk, Piotr - 131389
dc.contributor.authorCegłowski, Michał
dc.date.accessioned2025-01-28T11:32:24Z
dc.date.available2025-01-28T11:32:24Z
dc.date.createdat2025-01-20T11:29:58Zen
dc.date.issued2025
dc.description.volume69
dc.identifier.articleid106894
dc.identifier.doi10.1016/j.jwpe.2024.106894
dc.identifier.eissn2214-7144
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/546379
dc.languageeng
dc.language.containereng
dc.rightsDodaję tylko opis bibliograficzny
dc.rights.licenceBez licencji otwartego dostępu
dc.subtypeArticle
dc.titleReal-world application of molecularly imprinted $TiO_2$-graphite photocatalysts : efficient pharmaceutical removal under energy-optimized LED system
dc.title.journalJournal of Water Process Engineering
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
This study introduces a novel approach to the selective degradation of pharmaceuticals in wastewater using a molecularly imprinted $TiO_{2}$-recycled graphite photocatalyst. The photocatalyst was synthesized through a rapid microwave-assisted method, incorporating recycled graphite from spent lithium-ion batteries and imprinting metronidazole (MNZ) as a template molecule. The addition of graphite improved charge separation and extended the excitation range of the photocatalyst, which was effectively utilized by a tailored LED light source. The system was tested in diverse wastewater environments, including primary sewage and hospital effluent, to assess its efficacy and selectivity. Photocatalytic degradation tests revealed that the molecularly imprinted photocatalyst (MIP) achieved over 60 % MNZ degradation in primary sewage within 60 min, significantly reducing the risk of pharmaceutical transfer to the biological stage of wastewater treatment. The photocatalyst exhibited excellent stability over multiple catalytic cycles, maintaining high performance with only minor decreases in efficiency. Furthermore, tests conducted on hospital wastewater confirmed the high selectivity of the MIP photocatalysts, achieving over 75 % MNZ degradation, showcasing their robustness in real-world, complex wastewater matrices. These results underscore the stability, selectivity, and superior performance of MIP-based $TiO_{2}-G$ photocatalysts, offering a sustainable and efficient solution for pharmaceutical removal in wastewater treatment applications.
dc.affiliation
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.author
Kubiak, Adam
dc.contributor.author
Jaruga, Marta
dc.contributor.author
Lusina, Aleksandra
dc.contributor.author
Nazim, Tomasz
dc.contributor.author
Sobańska, Kamila - 155916
dc.contributor.author
Pietrzyk, Piotr - 131389
dc.contributor.author
Cegłowski, Michał
dc.date.accessioned
2025-01-28T11:32:24Z
dc.date.available
2025-01-28T11:32:24Z
dc.date.createdaten
2025-01-20T11:29:58Z
dc.date.issued
2025
dc.description.volume
69
dc.identifier.articleid
106894
dc.identifier.doi
10.1016/j.jwpe.2024.106894
dc.identifier.eissn
2214-7144
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/546379
dc.language
eng
dc.language.container
eng
dc.rights
Dodaję tylko opis bibliograficzny
dc.rights.licence
Bez licencji otwartego dostępu
dc.subtype
Article
dc.title
Real-world application of molecularly imprinted $TiO_2$-graphite photocatalysts : efficient pharmaceutical removal under energy-optimized LED system
dc.title.journal
Journal of Water Process Engineering
dc.type
JournalArticle
dspace.entity.typeen
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