Incorporation of guanidinium ions in double-layered magnetic systems

2013
journal article
article
6
cris.lastimport.wos2024-04-09T22:13:23Z
dc.abstract.enThe incorporation of guanidinium ions $(Hgua^{+})$ in $Cu^{II}-M^V$ systems results in the formation of two isostructural coordination polymers (Hgua) $Cu^{II}[M^V(CN_8]$, M=W (1); Mo (2), which reveal a double-layered structure separated by guanidinium ions. The magnetic measurements reveal long range magnetic ordering with critical temperatures of 32.8 and 27.5 K for 1 and 2, respectively. Moreover, both assemblies exhibit hysteresis loops with coercive fields of 300 Oe for 1 and 50 Oe for 2, and a spin-flip transition around 120 Oe.pl
dc.affiliationWydział Chemii : Zakład Krystalochemii i Krystalofizykipl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiegopl
dc.contributor.authorStefańczyk, Olaf - 107491 pl
dc.contributor.authorMajcher, Anna - 103619 pl
dc.contributor.authorRams, Michał - 100567 pl
dc.contributor.authorNitek, Wojciech - 130975 pl
dc.contributor.authorKozieł, Marcin - 133981 pl
dc.contributor.authorŁasocha, Wiesław - 130062 pl
dc.contributor.authorSieklucka, Barbara - 131848 pl
dc.date.accessioned2015-05-27T12:56:46Z
dc.date.available2015-05-27T12:56:46Z
dc.date.issued2013pl
dc.description.number14pl
dc.description.physical5042-5046pl
dc.description.volume42pl
dc.identifier.doi10.1039/C2DT32397Dpl
dc.identifier.eissn1477-9234pl
dc.identifier.issn1477-9226pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/8270
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licenceBez licencji otwartego dostępu
dc.source.integratorfalse
dc.subtypeArticlepl
dc.titleIncorporation of guanidinium ions in $Cu^{II}-[M^V(CN)_8]^{3-}$ double-layered magnetic systemspl
dc.title.journalDalton Transactionspl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T22:13:23Z
dc.abstract.enpl
The incorporation of guanidinium ions $(Hgua^{+})$ in $Cu^{II}-M^V$ systems results in the formation of two isostructural coordination polymers (Hgua) $Cu^{II}[M^V(CN_8]$, M=W (1); Mo (2), which reveal a double-layered structure separated by guanidinium ions. The magnetic measurements reveal long range magnetic ordering with critical temperatures of 32.8 and 27.5 K for 1 and 2, respectively. Moreover, both assemblies exhibit hysteresis loops with coercive fields of 300 Oe for 1 and 50 Oe for 2, and a spin-flip transition around 120 Oe.
dc.affiliationpl
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.affiliationpl
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorpl
Stefańczyk, Olaf - 107491
dc.contributor.authorpl
Majcher, Anna - 103619
dc.contributor.authorpl
Rams, Michał - 100567
dc.contributor.authorpl
Nitek, Wojciech - 130975
dc.contributor.authorpl
Kozieł, Marcin - 133981
dc.contributor.authorpl
Łasocha, Wiesław - 130062
dc.contributor.authorpl
Sieklucka, Barbara - 131848
dc.date.accessioned
2015-05-27T12:56:46Z
dc.date.available
2015-05-27T12:56:46Z
dc.date.issuedpl
2013
dc.description.numberpl
14
dc.description.physicalpl
5042-5046
dc.description.volumepl
42
dc.identifier.doipl
10.1039/C2DT32397D
dc.identifier.eissnpl
1477-9234
dc.identifier.issnpl
1477-9226
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/8270
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
Bez licencji otwartego dostępu
dc.source.integrator
false
dc.subtypepl
Article
dc.titlepl
Incorporation of guanidinium ions in $Cu^{II}-[M^V(CN)_8]^{3-}$ double-layered magnetic systems
dc.title.journalpl
Dalton Transactions
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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