Simple view
Full metadata view
Authors
Statistics
Unusual adsorption behavior of volatile hydrocarbons on MOF-5 studied using thermodesorption methods
Journal
Thermochimica Acta
Author
Volume
587
Pages
1-10
ISSN
0040-6031
eISSN
1872-762X
Keywords in English
MOF-5
QE-TPDA
porosity
thermodesorption
hydrocarbons
Language
English
Journal language
English
Abstract in English
Adsorption of n -alkanes (C 5 –C 10 ), isooctane, benzene, toluene and p-xylene on MOF-5 was studied by means of quasi-equilibrated temperature programmed desorption and adsorption (QE-TPDA) and temperature programmed desorption (TPD). Unusual thermodesorption profiles showing increasing complexity with the size of a probe molecule have been observed. Number of peaks in the ther- modesorption profile increased from one for pentane or benzene to five for decane. Considerable adsorption–desorption hysteresis was found for isooctane. These unusual thermodesorption profiles were discussed in comparison to those obtained for zeolites and ordered mesoporous silicas.
Affiliation
Wydział Chemii : Zakład Krystalochemii i KrystalofizykiWydział Chemii : Zakład Chemii NieorganicznejWydział Chemii : Zakład Technologii Chemicznej
Scopus© citations
19
| dc.abstract.en | Adsorption of n -alkanes (C 5 –C 10 ), isooctane, benzene, toluene and p-xylene on MOF-5 was studied by means of quasi-equilibrated temperature programmed desorption and adsorption (QE-TPDA) and temperature programmed desorption (TPD). Unusual thermodesorption profiles showing increasing complexity with the size of a probe molecule have been observed. Number of peaks in the ther- modesorption profile increased from one for pentane or benzene to five for decane. Considerable adsorption–desorption hysteresis was found for isooctane. These unusual thermodesorption profiles were discussed in comparison to those obtained for zeolites and ordered mesoporous silicas. | pl |
| dc.affiliation | Wydział Chemii : Zakład Krystalochemii i Krystalofizyki | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.affiliation | Wydział Chemii : Zakład Technologii Chemicznej | pl |
| dc.contributor.author | Makowski, Wacław - 100616 | pl |
| dc.contributor.author | Mańko, Maria | pl |
| dc.contributor.author | Zabierowski, Piotr - 107039 | pl |
| dc.contributor.author | Mlekodaj, Kinga - 108033 | pl |
| dc.contributor.author | Majda, Dorota - 130211 | pl |
| dc.contributor.author | Szklarzewicz, Janusz - 132237 | pl |
| dc.contributor.author | Łasocha, Wiesław - 130062 | pl |
| dc.date.accessioned | 2015-06-11T10:42:49Z | |
| dc.date.available | 2015-06-11T10:42:49Z | |
| dc.date.issued | 2014 | pl |
| dc.description.admin | [AB] Mańko, Maria 50000141 | pl |
| dc.description.admin | [AB] Mlekodaj, Kinga [SAP14005639] 50000141 | pl |
| dc.description.physical | 1-10 | pl |
| dc.description.volume | 587 | pl |
| dc.identifier.doi | 10.1016/j.tca.2014.04.016 | pl |
| dc.identifier.eissn | 1872-762X | pl |
| dc.identifier.issn | 0040-6031 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9420 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights.licence | Bez licencji otwartego dostępu | |
| dc.subject.en | MOF-5 | pl |
| dc.subject.en | QE-TPDA | pl |
| dc.subject.en | porosity | pl |
| dc.subject.en | thermodesorption | pl |
| dc.subject.en | hydrocarbons | pl |
| dc.subtype | Article | pl |
| dc.title | Unusual adsorption behavior of volatile hydrocarbons on MOF-5 studied using thermodesorption methods | pl |
| dc.title.journal | Thermochimica Acta | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
dc.abstract.enpl
Adsorption
of
n
-alkanes
(C
5
–C
10
),
isooctane,
benzene,
toluene
and
p-xylene
on
MOF-5
was
studied
by
means
of
quasi-equilibrated
temperature
programmed
desorption
and
adsorption
(QE-TPDA)
and
temperature
programmed
desorption
(TPD).
Unusual
thermodesorption
profiles
showing
increasing
complexity
with
the
size
of
a
probe
molecule
have
been
observed.
Number
of
peaks
in
the
ther-
modesorption
profile
increased
from
one
for
pentane
or
benzene
to
five
for
decane.
Considerable
adsorption–desorption
hysteresis
was
found
for
isooctane.
These
unusual
thermodesorption
profiles
were
discussed
in
comparison
to
those
obtained
for
zeolites
and
ordered
mesoporous
silicas. dc.affiliationpl
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej dc.affiliationpl
Wydział Chemii : Zakład Technologii Chemicznej dc.contributor.authorpl
Makowski, Wacław - 100616 dc.contributor.authorpl
Mańko, Maria dc.contributor.authorpl
Zabierowski, Piotr - 107039 dc.contributor.authorpl
Mlekodaj, Kinga - 108033 dc.contributor.authorpl
Majda, Dorota - 130211 dc.contributor.authorpl
Szklarzewicz, Janusz - 132237 dc.contributor.authorpl
Łasocha, Wiesław - 130062 dc.date.accessioned
2015-06-11T10:42:49Z dc.date.available
2015-06-11T10:42:49Z dc.date.issuedpl
2014 dc.description.adminpl
[AB] Mańko, Maria 50000141 dc.description.adminpl
[AB] Mlekodaj, Kinga [SAP14005639] 50000141 dc.description.physicalpl
1-10 dc.description.volumepl
587 dc.identifier.doipl
10.1016/j.tca.2014.04.016 dc.identifier.eissnpl
1872-762X dc.identifier.issnpl
0040-6031 dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9420 dc.languagepl
eng dc.language.containerpl
eng dc.rights.licence
Bez licencji otwartego dostępu dc.subject.enpl
MOF-5 dc.subject.enpl
QE-TPDA dc.subject.enpl
porosity dc.subject.enpl
thermodesorption dc.subject.enpl
hydrocarbons dc.subtypepl
Article dc.titlepl
Unusual adsorption behavior of volatile hydrocarbons on MOF-5 studied using thermodesorption methods dc.title.journalpl
Thermochimica Acta dc.typepl
JournalArticle dspace.entity.type
Publication Affiliations
Wydział Chemii
Makowski, Wacław
Mlekodaj, Kinga
Majda, Dorota
Szklarzewicz, Janusz
Łasocha, Wiesław
Mańko, Maria
Zabierowski, Piotr
* The migration of download and view statistics prior to the date of April 8, 2024 is in progress.
Views
10
Views per month
Views per city
Dublin
2
Wroclaw
2
Ashburn
1
Szczecin
1