The catalytic activity of bimetallic FeCoBEA zeolite catalysts in Fischer-Tropsch synthesis : the role of cobalt in framework position of dealuminated SiBEA zeolite

2024
journal article
article
dc.abstract.enTwo series of BEA zeolite modified with transition metals (Co and Fe) with different metals loadings were obtained: the first one was prepared by classical sequential wet impregnation to obtain C-Fe$_{x}$Co$_{y}$AlBEA catalysts; the second one was obtained by a two-step postsynthesis method to design C-Fe$_{x}$Co$_{y}$SiBEA catalysts. The catalytic activity of both series of FeCoBEA zeolite catalysts was determined by the FTS process. These bimetallic catalysts appear to combine the advantages of monometallic cobalt catalysts (lower selectivity towards CO$_{2}$ than for monometallic iron catalysts) and iron catalysts (lower selectivity towards CH$_{4}$ than for monometallic cobalt catalysts), while minimizing their disadvantages, such as the large amount of carbon deposition.
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorChałupka-Śpiewak, Karolina A.
dc.contributor.authorGurgul, Jacek
dc.contributor.authorGrams, Jacek
dc.contributor.authorMierczyński, Paweł
dc.contributor.authorManiukiewicz, Waldemar
dc.contributor.authorSzynkowska-Jóźwik, Małgorzata I.
dc.contributor.authorŁątka, Kazimierz - 100050
dc.contributor.authorRynkowski, Jacek
dc.contributor.authorDźwigaj, Stanisław
dc.date.accessioned2025-02-21T15:37:14Z
dc.date.available2025-02-21T15:37:14Z
dc.date.createdat2025-02-21T13:55:28Zen
dc.date.issued2024
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.versionostateczna wersja wydawcy
dc.description.volume192
dc.identifier.articleid206935
dc.identifier.doi10.1016/j.apcato.2024.206935
dc.identifier.eissn2950-6484
dc.identifier.issn2950-6492
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/549193
dc.languageeng
dc.language.containereng
dc.rightsUdzielam licencji. Uznanie autorstwa - Użycie niekomercyjne 4.0 Międzynarodowa
dc.rights.licenceCC-BY-NC
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/legalcode.pl
dc.share.typeotwarte czasopismo
dc.subject.enBEA zeolite
dc.subject.enFischer-Tropsch synthesis
dc.subject.encobalt catalysts
dc.subject.eniron catalysts
dc.subject.enbimetallic iron‑cobalt catalysts
dc.subtypeArticle
dc.titleThe catalytic activity of bimetallic FeCoBEA zeolite catalysts in Fischer-Tropsch synthesis : the role of cobalt in framework position of dealuminated SiBEA zeolite
dc.title.journalApplied Catalysis O: Open
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
Two series of BEA zeolite modified with transition metals (Co and Fe) with different metals loadings were obtained: the first one was prepared by classical sequential wet impregnation to obtain C-Fe$_{x}$Co$_{y}$AlBEA catalysts; the second one was obtained by a two-step postsynthesis method to design C-Fe$_{x}$Co$_{y}$SiBEA catalysts. The catalytic activity of both series of FeCoBEA zeolite catalysts was determined by the FTS process. These bimetallic catalysts appear to combine the advantages of monometallic cobalt catalysts (lower selectivity towards CO$_{2}$ than for monometallic iron catalysts) and iron catalysts (lower selectivity towards CH$_{4}$ than for monometallic cobalt catalysts), while minimizing their disadvantages, such as the large amount of carbon deposition.
dc.affiliation
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.author
Chałupka-Śpiewak, Karolina A.
dc.contributor.author
Gurgul, Jacek
dc.contributor.author
Grams, Jacek
dc.contributor.author
Mierczyński, Paweł
dc.contributor.author
Maniukiewicz, Waldemar
dc.contributor.author
Szynkowska-Jóźwik, Małgorzata I.
dc.contributor.author
Łątka, Kazimierz - 100050
dc.contributor.author
Rynkowski, Jacek
dc.contributor.author
Dźwigaj, Stanisław
dc.date.accessioned
2025-02-21T15:37:14Z
dc.date.available
2025-02-21T15:37:14Z
dc.date.createdaten
2025-02-21T13:55:28Z
dc.date.issued
2024
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.version
ostateczna wersja wydawcy
dc.description.volume
192
dc.identifier.articleid
206935
dc.identifier.doi
10.1016/j.apcato.2024.206935
dc.identifier.eissn
2950-6484
dc.identifier.issn
2950-6492
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/549193
dc.language
eng
dc.language.container
eng
dc.rights
Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne 4.0 Międzynarodowa
dc.rights.licence
CC-BY-NC
dc.rights.uri
http://creativecommons.org/licenses/by-nc/4.0/legalcode.pl
dc.share.type
otwarte czasopismo
dc.subject.en
BEA zeolite
dc.subject.en
Fischer-Tropsch synthesis
dc.subject.en
cobalt catalysts
dc.subject.en
iron catalysts
dc.subject.en
bimetallic iron‑cobalt catalysts
dc.subtype
Article
dc.title
The catalytic activity of bimetallic FeCoBEA zeolite catalysts in Fischer-Tropsch synthesis : the role of cobalt in framework position of dealuminated SiBEA zeolite
dc.title.journal
Applied Catalysis O: Open
dc.type
JournalArticle
dspace.entity.typeen
Publication
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