The paper presents a comprehensive analysis of pottery and lithic materials found in archaeological features associated with an Early Neolithic house from Biskupice (southern Poland) to shed light on exchange networks of the first farmers in Central Europe. The research began with the discovery of a unique fragment of a face vessel made in the Želiezovce style, a motif primarily found in Moravia and north-eastern Austria. Therefore, specialised analyses were undertaken to determine whether the Biskupice fragment was locally produced or originated from areas south of the Sudetes and Carpathians. The study involved an examination of raw clay material and the technology used to create the anthropomorphic vessel, aiming to establish its provenance (local production versus import). Petrographic methods were employed to analyse a diverse group of vessel types for comparison. Additionally, a selected group of pottery fragments, including the face vessel, underwent lipid residue analysis to determine their potential use. The combination of microscopic examinations and lipid residues analysis was utilised to study the link between the physical properties and function of the vessels. Finally, the archaeological context of other artifacts from the same house, including lithic assemblages, was investigated to determine the presence of both local and imported raw materials in Biskupice. The main conclusion of the study indicates local production of pottery, including the face vessel, and lithic implements. Conversely, a Transcarpathian transfer of some technological and decorative ideas, as well as imports of raw material such as obsidian, were confirmed.