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An integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-water

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An integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-water

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dc.contributor.author Aresta, Michele pl
dc.contributor.author Dibenedetto, Angela pl
dc.contributor.author Baran, Tomasz [USOS63432] pl
dc.contributor.author Angelini, Antonella pl
dc.contributor.author Łabuz, Przemysław [SAP13903290] pl
dc.contributor.author Macyk, Wojciech [SAP11116781] pl
dc.date.accessioned 2015-06-22T08:03:13Z
dc.date.available 2015-06-22T08:03:13Z
dc.date.issued 2014 pl
dc.identifier.issn 2195-951X pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/9925
dc.language eng pl
dc.rights Udzielam licencji. Uznanie autorstwa 2.0 *
dc.rights.uri http://creativecommons.org/licenses/by/2.0/pl/legalcode *
dc.title An integrated photocatalytic/enzymatic system for the reduction of $CO_2$ to methanol bioglycerol-water pl
dc.type JournalArticle pl
dc.description.physical 2556-2565 pl
dc.identifier.weblink https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-267.pdf pl
dc.abstract.en A hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application. pl
dc.subject.en $CO_2$ chemistry pl
dc.subject.en NADH regeneration pl
dc.subject.en electron transfer pl
dc.subject.en photochemistry pl
dc.subject.en enzymatic $CO_2$ reduction pl
dc.subject.en photosensitization pl
dc.description.volume 10 pl
dc.identifier.doi 10.3762/bjoc.10.267 pl
dc.identifier.eissn 1860-5397 pl
dc.title.journal Beilstein Journal of Organic Chemistry pl
dc.language.container eng pl
dc.date.accession 2019-05-13 pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl
dc.rights.original CC-BY; otwarte czasopismo; ostateczna wersja wydawcy; w momencie opublikowania; 0; pl
dc.identifier.project ROD UJ / P pl
.pointsMNiSW [2014 A]: 30


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Udzielam licencji. Uznanie autorstwa 2.0 Except where otherwise noted, this item's license is described as Udzielam licencji. Uznanie autorstwa 2.0