Biomimetic direct aldol reaction of pyruvate esters with chiral aldehydes

Bibliographic description

punktacja MEiN [2013 A]: 45

title:	Biomimetic direct aldol reaction of pyruvate esters with chiral aldehydes
author:	El-Sepelgy Osama , Młynarski Jacek
journal title:	Advanced Synthesis & Catalysis
volume:	355
issue:	2-3
date of publication :	2013
pages:	281-286
ISSN:	1615-4150
eISSN:	1615-4169
DOI:	10.1002/adsc.201200914
language:	English
journal language:	English
abstract in English:	Direct aldol reactions of pyruvate esters with sugar aldehydes is efficiently promoted by dinuclear metal complexes or chiral Cinchona alkaloid organocatalysts. Application of sterically hindered aryl esters enables the to-date problematic aldol reaction of pyruvate donors with syn- or anti-selectivity en route to the short and efficient synthesis of 3-deoxy-2-ulosonic acids.
affiliation:	Wydział Chemii : Zakład Chemii Organicznej
type:	journal article
subtype:	academic paper

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