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Disentangling steric and electronic factors in monomeric bis(2-bromo-4-chloro-6-{[(2-hydroxyethyl)imino]methyl}phenolato-
crystal structure
square-planar complex
schiff base ligands
self-assembly
salicylidene-2- ethanolamine
graph-set analysis.
monomeric copper(II) complex
The title compound, [Cu(C_9H_8BrClNO_2)_2], is a square-planar complex. The potentially tridentate dibasic 2-bromo-4-chloro-6-{[(2-hydroxyethyl)imino]meth-yl}phenolate ligand coordinates in a trans-bis fashion to the CuII centre via the imine N and phenolate O atoms. The Cu^{II} atom lies on the centre of inversion of the mol-ecule. The potentially coordinating hydroxyethyl group remains protonated and uncoordinated, taking part in intermolecular hydrogen bonds with vicinal groups, leading to the formation of a two-dimensional hydrogen-bond network with sheets parallel to the (10 1) plane. Substituent effects on the crystal packing and coordination modes of the ligand are discussed.
dc.abstract.en | The title compound, [Cu(C_9H_8BrClNO_2)_2], is a square-planar complex. The potentially tridentate dibasic 2-bromo-4-chloro-6-{[(2-hydroxyethyl)imino]meth-yl}phenolate ligand coordinates in a trans-bis fashion to the CuII centre via the imine N and phenolate O atoms. The Cu^{II} atom lies on the centre of inversion of the mol-ecule. The potentially coordinating hydroxyethyl group remains protonated and uncoordinated, taking part in intermolecular hydrogen bonds with vicinal groups, leading to the formation of a two-dimensional hydrogen-bond network with sheets parallel to the (10 1) plane. Substituent effects on the crystal packing and coordination modes of the ligand are discussed. | pl |
dc.affiliation | Wydział Chemii : Zakład Krystalochemii i Krystalofizyki | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.contributor.author | Zabierowski, Piotr - 107039 | pl |
dc.contributor.author | Szklarzewicz, Janusz - 132237 | pl |
dc.contributor.author | Nitek, Wojciech - 130975 | pl |
dc.date.accessioned | 2015-06-11T07:54:42Z | |
dc.date.available | 2015-06-11T07:54:42Z | |
dc.date.issued | 2014 | pl |
dc.description.number | 7 | pl |
dc.description.physical | 659-661 | pl |
dc.description.volume | C70 | pl |
dc.identifier.doi | 10.1107/S2053229614012273 | pl |
dc.identifier.eissn | 1600-5759 | pl |
dc.identifier.issn | 0108-2701 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9338 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights.licence | bez licencji | |
dc.subject.en | crystal structure | pl |
dc.subject.en | square-planar complex | pl |
dc.subject.en | schiff base ligands | pl |
dc.subject.en | self-assembly | pl |
dc.subject.en | salicylidene-2- ethanolamine | pl |
dc.subject.en | graph-set analysis. | pl |
dc.subject.en | monomeric copper(II) complex | pl |
dc.subtype | Article | pl |
dc.title | Disentangling steric and electronic factors in monomeric bis(2-bromo-4-chloro-6-{[(2-hydroxyethyl)imino]methyl}phenolato-$\kappa^2$N,O)copper(II) | pl |
dc.title.journal | Acta Crystallographica. Section C, Crystal Structure Communications | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |