Disentangling steric and electronic factors in monomeric bis­(2-bromo-4-chloro-6-{[(2-hy­droxy­eth­yl)imino]­meth­yl}phenolato-N,O)copper(II)

2014
journal article
article
dc.abstract.enThe title compound, [Cu(C_9H_8BrClNO_2)_2], is a square-planar complex. The potentially tridentate dibasic 2-bromo-4-chloro-6-{[(2-hydroxyethyl)imino]meth-yl}phenolate ligand coordinates in a trans-bis fashion to the CuII centre via the imine N and phenolate O atoms. The Cu^{II} atom lies on the centre of inversion of the mol-ecule. The potentially coordinating hydroxyethyl group remains protonated and uncoordinated, taking part in intermolecular hydrogen bonds with vicinal groups, leading to the formation of a two-dimensional hydrogen-bond network with sheets parallel to the (10 1) plane. Substituent effects on the crystal packing and coordination modes of the ligand are discussed.pl
dc.affiliationWydział Chemii : Zakład Krystalochemii i Krystalofizykipl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorZabierowski, Piotr - 107039 pl
dc.contributor.authorSzklarzewicz, Janusz - 132237 pl
dc.contributor.authorNitek, Wojciech - 130975 pl
dc.date.accessioned2015-06-11T07:54:42Z
dc.date.available2015-06-11T07:54:42Z
dc.date.issued2014pl
dc.description.number7pl
dc.description.physical659-661pl
dc.description.volumeC70pl
dc.identifier.doi10.1107/S2053229614012273pl
dc.identifier.eissn1600-5759pl
dc.identifier.issn0108-2701pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/9338
dc.languageengpl
dc.language.containerengpl
dc.rights.licencebez licencji
dc.subject.encrystal structurepl
dc.subject.ensquare-planar complexpl
dc.subject.enschiff base ligandspl
dc.subject.enself-assemblypl
dc.subject.ensalicylidene-2- ethanolaminepl
dc.subject.engraph-set analysis.pl
dc.subject.enmonomeric copper(II) complexpl
dc.subtypeArticlepl
dc.titleDisentangling steric and electronic factors in monomeric bis­(2-bromo-4-chloro-6-{[(2-hy­droxy­eth­yl)imino]­meth­yl}phenolato-$\kappa^2$N,O)copper(II)pl
dc.title.journalActa Crystallographica. Section C, Crystal Structure Communicationspl
dc.typeJournalArticlepl
dspace.entity.typePublication
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