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Polyhedron
30
Author
Korzeniak Tomasz
Nowicka Beata
Stadnicka Katarzyna
Nitek Wojciech
Majcher Anna
Sieklucka Barbara
Title of volume
Special issue 100th anniversary of the award of the 1913 Nobel Prize in chemistry to Alfred Werner : a celebration
Volume
52
Pages
442-447
ISSN
0277-5387
eISSN
1873-3719
Keywords in English
molecular squares
bipyridinehexacyanotungstates
self-assembly
supramolecular interactions
crystal structure
Language
English
Container language
English
Abstract in English
Three new cyanido-bridged discrete bimetallic assemblies based on
Affiliation
Wydział Chemii : Zakład Chemii NieorganicznejWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana SmoluchowskiegoWydział Chemii : Zakład Krystalochemii i Krystalofizyki
| cris.lastimport.scopus | 2024-04-07T17:17:20Z | |
| cris.lastimport.wos | 2024-04-09T23:17:44Z | |
| dc.abstract.en | Three new cyanido-bridged discrete bimetallic assemblies based on $\left [ W\left ( CN \right )_{6}\left ( bpy \right ) \right ]^{2-}$ building block have been synthesised and structurally characterised. Neutral molecular square $\left \{ \left [ Ni\left ( bpy \right )_{2} \right ]_{2}\left [ W\left ( CN \right )_{6}\left ( bpy \right ) \right ]_{2} \right \}\cdot nH_{2}O \left ( 1 \right )\left ( bpy=2,{2}'-bipyridine \right )$ has been constructed from $\left [ Ni^{II} \left ( pby \right )_{2}\left ( H_{2}O_{2} \right )\right ]^{2+}$ complex. Since the attempt to obtain analogous structure with Cu(II) ion was unsuccessful, we introduced tetradentate blocking ligand tren (tren = tris(2-aminoethyl)amine) on Cu, which resulted in dinuclear molecule $\left \{ \left [ Cu\left ( tren \right ) \right ]\left [ W\left ( CN \right )_{6}\left ( bpy \right ) \right ] \right \}\left ( 2 \right )$. In order to create square cluster with Cu(II) ions we employed tridentate ligand di-(2-picolyl)amine (dpa), which yielded the desired structure of $\left \{ \left [ Cu\left ( dpa \right ) \right ]_{2} \left [ W\left ( CN \right )_{6}\left ( bpy \right ) \right ]_{2}\right \} \left ( 3 \right )$. Compounds (1) and (3), the first molecular squares based on $\left [ W\left ( CN \right )_{6}\left ( bpy \right ) \right ]^{2-}$ building block, are paramagnetic and follow the Curie law. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.affiliation | Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego | pl |
| dc.affiliation | Wydział Chemii : Zakład Krystalochemii i Krystalofizyki | pl |
| dc.contributor.author | Korzeniak, Tomasz - 129164 | pl |
| dc.contributor.author | Nowicka, Beata - 131056 | pl |
| dc.contributor.author | Stadnicka, Katarzyna - 132048 | pl |
| dc.contributor.author | Nitek, Wojciech - 130975 | pl |
| dc.contributor.author | Majcher, Anna - 103619 | pl |
| dc.contributor.author | Sieklucka, Barbara - 131848 | pl |
| dc.date.accessioned | 2015-05-21T13:14:19Z | |
| dc.date.available | 2015-05-21T13:14:19Z | |
| dc.date.issued | 2013 | pl |
| dc.description.admin | [AB] Stadnicka, Katarzyna [SAP11004149] 50000141 | pl |
| dc.description.physical | 442-447 | pl |
| dc.description.volume | 52 | pl |
| dc.identifier.doi | 10.1016/j.poly.2012.08.053 | pl |
| dc.identifier.eissn | 1873-3719 | pl |
| dc.identifier.issn | 0277-5387 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/7708 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights | Dodaję tylko opis bibliograficzny | * |
| dc.rights.licence | bez licencji | |
| dc.rights.uri | * | |
| dc.subject.en | molecular squares | pl |
| dc.subject.en | bipyridinehexacyanotungstates | pl |
| dc.subject.en | self-assembly | pl |
| dc.subject.en | supramolecular interactions | pl |
| dc.subject.en | crystal structure | pl |
| dc.subtype | Article | pl |
| dc.title | Construction of $CN^{-}$-bridged molecular squares employing penta-, hexa- and octa-coordinated metal ions | pl |
| dc.title.journal | Polyhedron | pl |
| dc.title.volume | Special issue 100th anniversary of the award of the 1913 Nobel Prize in chemistry to Alfred Werner : a celebration | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
Affiliations
Wydział Chemii
Korzeniak, Tomasz
Nowicka, Beata
Stadnicka, Katarzyna
Nitek, Wojciech
Sieklucka, Barbara
Wydział Fizyki, Astronomii i Informatyki Stosowanej
Majcher, Anna