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SBA-15 mesoporous silicas modified with rhodium were studied as catalysts for the N2O decomposition reaction. Rhodium was deposited on SBA-15 by the Molecular Designed Dispersion (MDD) method using Rh(acac)3 as a precursor of active phase. The same method was used for the deposition of Cu, Fe, Al and Ti. The SBA-15 support modified with metals were characterized with respect to metal loading (EPMA), structure (XRD), texture (BET), morphology (SEM), Rh dispersion (oxygen chemisorption), surface acidity (pyridine adsorption) and chemical nature of introduced copper and iron species (UV-vis-DRS). The rhodium-containing SBA-15 samples were found to be active catalysts for the N2O decomposition reaction. Deposition of Al on the Rh-loaded catalyst increased its activity. An opposite effect was observed for the samples modified with Cu and Fe.
słowa kluczowe w j. angielskim:
$N_2O$ decomposition, SBA-15, rhodium, MDD method
wydział: instytut / zakład / katedra:
Wydział Biologii i Nauk o Ziemi : Instytut Nauk Geologicznych, Wydział Chemii : Zakład Technologii Chemicznej