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Influence of acrylic polymers stereoregularity on interface interactions in model thin film systems

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Influence of acrylic polymers stereoregularity on interface interactions in model thin film systems

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dc.contributor.author Marzec, Mateusz M. pl
dc.contributor.author Awsiuk, Kamil [SAP14001148] pl
dc.contributor.author Dąbczyński, Paweł [USOS128849] pl
dc.contributor.author Rysz, Jakub [SAP11116295] pl
dc.contributor.author Budkowski, Andrzej [SAP11011875] pl
dc.contributor.author Bernasik, Andrzej pl
dc.date.accessioned 2018-10-24T09:11:44Z
dc.date.available 2018-10-24T09:11:44Z
dc.date.issued 2018 pl
dc.identifier.issn 1022-1352 pl
dc.identifier.uri https://ruj.uj.edu.pl/xmlui/handle/item/58596
dc.language eng pl
dc.rights Dodaję tylko opis bibliograficzny *
dc.rights.uri *
dc.title Influence of acrylic polymers stereoregularity on interface interactions in model thin film systems pl
dc.type JournalArticle pl
dc.abstract.en The origin and formation of the dipole moment at the interface of metal electrode and thin organic film is crucial for the fabrication of high‐performance organic electronic devices. In this work, model polymer multilayer systems are studied in which interfaces are modified heterogeneously with thiol‐based self‐assembled monolayers (SAM). Due to the presence of polar terminal group (‐COOH) in SAM and polar pendant groups (‐COOH, ‐C(O)OCH_{3}) within studied polymers, it is pointed out that the resultant interface energetics differ from the expected ones as one would expect from the chemical character of the self‐assembled molecules used to tune junction properties. This is discussed in terms of inter‐association and depolarization effects between polymer and thiol modified substrate. The presented model systems may serve as an interaction reference for SAMs and semiconducting polymers containing similar moieties, utilized for the fabrication of organic electronic devices. pl
dc.description.volume 219 pl
dc.description.number 15 pl
dc.identifier.doi 10.1002/macp.201800097 pl
dc.identifier.eissn 1521-3935 pl
dc.title.journal Macromolecular Chemistry and Physics pl
dc.language.container eng pl
dc.affiliation Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego pl
dc.subtype Article pl
dc.identifier.articleid 1800097 pl
dc.rights.original bez licencji pl
dc.identifier.project 2013/09/N/ST5/00874 pl
dc.identifier.project ROD UJ / O pl
.pointsMNiSW [2018 A]: 35


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