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Polymeric/silicagel hybrid molecularly photoimprinted adsorbents for adenosine and its derivatives

Polymeric/silicagel hybrid molecularly photoimprinted ...

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dc.contributor.author Mikulska, Anna pl
dc.contributor.author Inoue, Masamichi pl
dc.contributor.author Kuroda, Keita pl
dc.contributor.author Gut, Agnieszka [USOS102458] pl
dc.contributor.author Yusa, Shin-Ichi pl
dc.contributor.author Nowakowska, Maria [SAP11005597] pl
dc.contributor.author Szczubiałka, Krzysztof [SAP11014318] pl
dc.date.accessioned 2015-01-15T11:13:07Z
dc.date.available 2015-01-15T11:13:07Z
dc.date.issued 2014 pl
dc.identifier.issn 0014-3057 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/2566
dc.language eng pl
dc.title Polymeric/silicagel hybrid molecularly photoimprinted adsorbents for adenosine and its derivatives pl
dc.type JournalArticle pl
dc.description.physical 230-238 pl
dc.description.additional Na publikacji autorka Gut Agnieszka podpisana jako Iwanowska Agnieszka. pl
dc.abstract.en The adsorbents of adenosine, a potential cancer biomarker present in physiological fluids, urine in particular, were obtained and studied. The adsorbents were fabricated by coating submicron-sized silica gel particles with ultrathin layers of polymers containing thymine moieties. The thymine groups selectively adsorbed compounds containing adenine, a nucleobase complementary to thymine, via the formation of hydrogen bonds. Irradiation of the adsorbents with light selectively absorbed by thymine chromophores in the presence of adenine as a template molecule resulted in the photochemical molecular imprinting of adenine. The non-imprinted adsorbent showed preferential adenosine adsorption from a solution containing a mixture of nucleosides. The adenine-imprinted materials showed considerably higher than non-imprinted adsorbents selectivity of adenosine adsorption versus other nucleosides. pl
dc.subject.en adeninea pl
dc.subject.en adenosine pl
dc.subject.en adsorbent pl
dc.subject.en molecular imprinting pl
dc.subject.en photodimerization pl
dc.subject.en thymine pl
dc.description.volume 59 pl
dc.identifier.doi 10.1016/j.eurpolymj.2014.07.029 pl
dc.identifier.eissn 1873-1945 pl
dc.title.journal European Polymer Journal pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Fizycznej i Elektrochemii pl
dc.subtype Article pl
dc.rights.original bez licencji pl
dc.pbn.affiliation USOS102458:UJ.WCh; pl
.pointsMNiSW [2014 A]: 35


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