Repozytorium Uniwersytetu Jagiellońskiego

Role of iron and chromium complexes in environmental self‐cleaning processes

Role of iron and chromium complexes in environmental ...

Metadane (Dublin Core) Cieśla, Paweł pl Mytych, Piotr pl Kocot, Przemysław pl Stasicka, Zofia pl 2015-01-15T09:30:13Z 2015-01-15T09:30:13Z 2007 pl
dc.identifier.issn 0149-6395 pl
dc.language eng pl
dc.title Role of iron and chromium complexes in environmental self‐cleaning processes pl
dc.type JournalArticle pl
dc.description.physical 1651-1666 pl
dc.abstract.en The present research includes solar‐light‐driven photocatalytic cycles based on the photoreductions of Fe(III), Cr(VI), and Cr(III) compounds with EDTA, oxalate and other ligands. Molecular oxygen is needed to close the photocatalytic cycles in which the metal species plays a role of photocatalyst; it affects the reaction mechanism and rate. The photoinduced electron transfer was also investigated in the presence of some external electron donors, such as EDTA, aliphatic alcohols, phenol, and its halogen derivatives, oxalate, nitrate(III), sulfate(IV). The results apply to the removal of such hazardous environmental pollutants as chromate(VI) or phenol derivatives and such recalcitrant pollutants as EDTA. pl
dc.subject.en chromium(III) complexes pl
dc.subject.en chromate(VI) pl
dc.subject.en EDTA pl
dc.subject.en iron(III) complexes pl
dc.subject.en phenol pl
dc.subject.en photocatalysis pl
dc.subject.en photoredox pl
dc.description.volume 42 pl
dc.description.number 7 pl
dc.identifier.doi 10.1080/01496390701290540 pl
dc.identifier.eissn 1520-5754 pl
dc.title.journal Separation Science and Technology pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl

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