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On-surface synthesis with atomic hydrogen

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On-surface synthesis with atomic hydrogen

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dc.contributor.author Zuzak, Rafał [SAP14004865] pl
dc.contributor.author Jančařík, Andrej pl
dc.contributor.author Gourdon, Andre pl
dc.contributor.author Szymoński, Marek [SAP11006649] pl
dc.contributor.author Godlewski, Szymon [SAP13903357] pl
dc.date.accessioned 2020-11-06T17:08:47Z
dc.date.available 2020-11-06T17:08:47Z
dc.date.issued 2020 pl
dc.identifier.issn 1936-0851 pl
dc.identifier.uri https://ruj.uj.edu.pl/xmlui/handle/item/252910
dc.language eng pl
dc.rights Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa *
dc.rights.uri http://creativecommons.org/licenses/by/4.0/pl/legalcode *
dc.title On-surface synthesis with atomic hydrogen pl
dc.type JournalArticle pl
dc.description.physical 13316-13323 pl
dc.description.additional Correction: ACS Nano 2020, 14 (10), 14251-14252, DOI: 10.1021/acsnano.0c08048 pl
dc.abstract.en Surface-assisted synthesis has become a powerful approach for generation of molecular nanostructures, which could not be obtained via traditional solution chemistry. Nowadays there is an intensive search for reactions that could proceed on flat surfaces in order to boost the versatility and applicability of synthesized nano-objects. Here we propose application of atomic hydrogen combined with on-surface synthesis in order to tune the reaction pathways. We demonstrate that atomic hydrogen could be widely applied: (1) as a cleaning tool, which allows removal of halogen residues from the surface after Ullmann couplings/polymerization, (2) by reaction with surface organometallics to provide stable hydrogenated species, and (3) as a reagent for debromination or desulfurization of adsorbed species. pl
dc.subject.en on-surface synthesis pl
dc.subject.en graphene nanoribbon pl
dc.subject.en hydrogenation pl
dc.subject.en atomic hydrogen pl
dc.subject.en molecular polymers pl
dc.subject.en organometallic state pl
dc.description.volume 14 pl
dc.description.number 10 pl
dc.identifier.doi 10.1021/acsnano.0c05160 pl
dc.identifier.eissn 1936-086X pl
dc.title.journal ACS Nano pl
dc.language.container eng pl
dc.affiliation Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego pl
dc.subtype Article pl
dc.rights.original CC-BY; inne; ostateczna wersja wydawcy; w momencie opublikowania; 0 pl
dc.identifier.project ROD UJ / OP pl
.pointsMNiSW [2020 A]: 200


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Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa Except where otherwise noted, this item's license is described as Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa