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Singlet oxygen photogeneration at surface modified titanium dioxide

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Singlet oxygen photogeneration at surface modified titanium dioxide

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dc.contributor.author Kyzioł, Agnieszka [SAP11019297] pl
dc.contributor.author Krakowska, Elżbieta pl
dc.contributor.author Stochel, Grażyna [SAP11011061] pl
dc.contributor.author Macyk, Wojciech [SAP11116781] pl
dc.date.accessioned 2014-12-23T16:29:15Z
dc.date.available 2014-12-23T16:29:15Z
dc.date.issued 2006 pl
dc.identifier.issn 0002-7863 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/2407
dc.language eng pl
dc.title Singlet oxygen photogeneration at surface modified titanium dioxide pl
dc.type JournalArticle pl
dc.description.physical 15574-15575 pl
dc.description.additional Na publikacji autorka Kyzioł Agnieszka podpisana jako Jańczyk Agnieszka. pl
dc.abstract.en Abstract Image Substitution of surface −OH groups of TiO2 may influence competition between photoinduced energy and electron-transfer processes and lead to improved singlet oxygen generation. In contrast to neat TiO2, surface modified titanium dioxide can photocatalyze degradation of a very stable substance, cyanuric acid. Presented results are in contradiction to usually accepted hypothesis of the mechanism of cyanuric acid photodegradation in the presence of fluorinated TiO2 (F−TiO2) in which “bulk” hydroxyl radicals play a key role. It seems plausible that the difference of activity observed for TiO2 and F−TiO2 is not related to various types of generated hydroxyl radicals, but rather to competition between electron-transfer processes (formation of radicals) and energy-transfer processes (formation of singlet oxygen). pl
dc.description.volume 128 pl
dc.description.number 49 pl
dc.identifier.doi 10.1021/ja065970m pl
dc.identifier.eissn 1520-5126 pl
dc.title.journal Journal of the American Chemical Society pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl


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