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Photoassisted catalytic oxidation of carbon monoxide at room temperature

Photoassisted catalytic oxidation of carbon monoxide ...

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dc.contributor.author Macyk, Wojciech [SAP11116781] pl
dc.contributor.author Kisch, Horst pl
dc.date.accessioned 2014-12-18T08:56:35Z
dc.date.available 2014-12-18T08:56:35Z
dc.date.issued 2007 pl
dc.identifier.issn 0026-9247 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/2332
dc.language eng pl
dc.title Photoassisted catalytic oxidation of carbon monoxide at room temperature pl
dc.type JournalArticle pl
dc.description.physical 935-940 pl
dc.abstract.en The thermal and photoassisted catalytic oxidation of CO at metal oxide supported RuO 2 x H 2 O was studied at room temperature. Contrary to neat RuO 2 x H 2 O the support- ed catalysts suffer from fast deactivation attributed to strong adsorption of the reaction product carbon dioxide. The latter can be efficiently removed from the catalyst surface at ele- vated temperatures. In some cases, i.e . for catalysts supported with selected n -type semiconductors (TiO 2 ,SnO 2 ,WO 3 ), effi- cient CO 2 desorption and good, constant catalytic activity was observed upon visible light irradiation. Under such conditions the CO to CO 2 conversion observed for RuO 2 x H 2 O = TiO 2 was nearly as good and stable as for the unsupported catalyst. It is suggested that light absorption promotes carbon dioxide desorption through positive charging of the catalyst surface pl
dc.description.volume 138 pl
dc.description.number 10 pl
dc.identifier.doi 10.1007/s00706-007-0637-y pl
dc.identifier.eissn 1434-4475 pl
dc.title.journal Monatshefte für Chemie pl
dc.language.container ger pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl


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