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Visible light photocatalysis by a titania transition metal complex


Visible light photocatalysis by a titania transition metal complex

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dc.contributor.author Kisch, Horst pl
dc.contributor.author Burgeth, Gerald pl
dc.contributor.author Macyk, Wojciech [SAP11116781] pl
dc.date.accessioned 2014-12-16T13:37:52Z
dc.date.available 2014-12-16T13:37:52Z
dc.date.issued 2004 pl
dc.identifier.issn 0898-8838 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/2311
dc.language eng pl
dc.rights Dodaję tylko opis bibliograficzny *
dc.rights.uri *
dc.title Visible light photocatalysis by a titania transition metal complex pl
dc.type JournalArticle pl
dc.description.physical 241-259 pl
dc.abstract.en This chapter discusses visible light photocatalysis by a titania transition metal complex. Hexachloroplatinic acid in solution only induces a stoichiometric visible light photooxidation of the ubiquitous water pollutant 4-chlorophenol (4-CP), whereas, the reaction becomes photocatalytic when the complex is supported onto titania. It was found that the most active catalyst was obtained when the complex was covalently attached to titania. Different from a single crystal electrode, it is more difficult to measure the flatband potential of a semiconductor powder, which is necessary to estimate the absolute positions of the valence and conduction band edges. The degradation of atrazine in general affords cyanuric acid as the final product when the photocatalyst is an unmodified titania material. In the photodegradation with sunlight, a significant difference between the photocatalysts prepared by adsorption from solution and by grinding becomes apparent. pl
dc.description.volume 56 pl
dc.identifier.doi 10.1016/S0898-8838(04)56008-7 pl
dc.identifier.eissn 1557-8917 pl
dc.title.journal Advances in Inorganic Chemistry pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl
dc.rights.original bez licencji pl

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