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Catecholate and 2,3-acenediolate complexes of $d^{0}$ ions as prospective materials for molecular electronics and spintronics
pl
dc.type
JournalArticle
pl
dc.description.physical
1706-1731
pl
dc.abstract.en
Transition
metal
oxides
at
their
highest
oxidation
states
usually
show
semiconducting
properties.
The
most
notable
example
is
titanium
dioxide,
whereas
other
oxides
and
oxide
binary
phases
are
also
wide
band
gap
semiconductors.
These
materials
are
usually
studied
from
the
point
of
view
of
the
solid
state
chemistry
or
catalysis,
but
their
semiconducting
properties
upon
interaction
with
photosensitizers
are
not
well
recognized
with
the
notable
exception
of
titanium
dioxide.
Application
of
these
semiconductors
as
materials
for
switching
devices
is
also
not
well
recognized.
This
review
paper
describes
the
electronic
structure
and
reactivity
of
several
transition
metal
oxides
towards
2,3-dihydroxyacenes.
Furthermore,
a
simple
quantum-mechanical
model
for
the
description
of
such
systems
is
provided.
It
is
demonstrated
that
not
only
titanium
dioxide,
but
also
other
d
0
transition
metal
oxides
can
be
photosensitized
with
catechol-derived
ligands
and
that
the
properties
of
such
systems
are
strongly
affected
by
the
nature
of
the
ligand.
pl
dc.subject.en
wide band gap semiconductors
pl
dc.subject.en
acenes
pl
dc.subject.en
organic semiconductors
pl
dc.subject.en
catecholates
pl
dc.description.volume
256
pl
dc.description.number
15-16
pl
dc.description.points
50
pl
dc.identifier.doi
10.1016/j.ccr.2012.03.028
pl
dc.identifier.eissn
1873-3840
pl
dc.title.journal
Coordination Chemistry Reviews
pl
dc.title.volume
Special issue : 19th International Symposium on the Photophysics and Photochemistry of Coordination Compounds
pl
dc.language.container
eng
pl
dc.affiliation
Wydział Chemii : Zakład Chemii Nieorganicznej
pl
dc.subtype
ReviewArticle
pl
dc.rights.original
bez licencji
pl
.pointsMNiSW
[2012 A]: 50
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