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A new hybrid porphyrin-heteropolyacid material : synthesis, characterization and investigation as catalyst in Baeyer-Villiger oxidation : synergistic effect
organic-inorganic hybrid
poyoxometalate
cyclohexanone oxidation
porphyrin
A new tetraphenylporphyrin-tungstophosphoric acid hybrid was synthesized and physico-chemically characterized by different techniques. This hybrid, its molybdenum analogue, tungstophosphoric and molybdophosphoric acids as well as their Mn, Fe and Co salts were applied in Baeyer–Villiger oxidation of cyclohexanone to caprolactone with molecular oxygen. Due to the synergistic effect porphyrin-heteropolyacid hybrids exhibit similar catalytic activity as appropriate heteropoly salts and much higher activity than parent heteropolyacids.
cris.lastimport.wos | 2024-04-09T22:37:32Z | |
dc.abstract.en | A new tetraphenylporphyrin-tungstophosphoric acid hybrid was synthesized and physico-chemically characterized by different techniques. This hybrid, its molybdenum analogue, tungstophosphoric and molybdophosphoric acids as well as their Mn, Fe and Co salts were applied in Baeyer–Villiger oxidation of cyclohexanone to caprolactone with molecular oxygen. Due to the synergistic effect porphyrin-heteropolyacid hybrids exhibit similar catalytic activity as appropriate heteropoly salts and much higher activity than parent heteropolyacids. | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.contributor.author | Pamin, Katarzyna | pl |
dc.contributor.author | Prończuk, Mateusz | pl |
dc.contributor.author | Górecka, Sylwia - 175776 | pl |
dc.contributor.author | Kubiak, Władysław | pl |
dc.contributor.author | Sojka, Zbigniew - 131982 | pl |
dc.contributor.author | Połtowicz, Jan | pl |
dc.date.accessioned | 2015-12-11T10:40:59Z | |
dc.date.available | 2015-12-11T10:40:59Z | |
dc.date.issued | 2015 | pl |
dc.description.additional | Na publikacji autorka Górecka Sylwia podpisana jako Basąg Sylwia. | pl |
dc.description.physical | 13-16 | pl |
dc.description.volume | 59 | pl |
dc.identifier.doi | 10.1016/j.inoche.2015.06.005 | pl |
dc.identifier.eissn | 1879-0259 | pl |
dc.identifier.issn | 1387-7003 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/18121 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights.licence | bez licencji | |
dc.subject.en | organic-inorganic hybrid | pl |
dc.subject.en | poyoxometalate | pl |
dc.subject.en | cyclohexanone oxidation | pl |
dc.subject.en | porphyrin | pl |
dc.subtype | Article | pl |
dc.title | A new hybrid porphyrin-heteropolyacid material : synthesis, characterization and investigation as catalyst in Baeyer-Villiger oxidation : synergistic effect | pl |
dc.title.journal | Inorganic Chemistry Communications | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |