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Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species

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Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species

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dc.contributor.author Góra-Marek, Kinga [SAP11018751] pl
dc.date.accessioned 2015-09-24T07:24:50Z
dc.date.available 2015-09-24T07:24:50Z
dc.date.issued 2008 pl
dc.identifier.issn 0022-2860 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/15777
dc.language eng pl
dc.title Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species pl
dc.type JournalArticle pl
dc.description.physical 331-335 pl
dc.abstract.en The interaction of adsorbed probe molecules with Co2+ cations in exchange position were investigated in the skeletal transmission window region. The position of the band of oxygen ring perturbed by Co2+ provides information on the electron-acceptor properties of cation as well as the strength of interaction of cation with framework oxygens and with adsorbed molecules. The interaction of Co2+ with CO, NO, H2O, ammonia, acetylene, ethene, benzene and formaldehyde was investigated. The role of σ donation and π back donation in the interaction of CO and organic molecules was discussed. pl
dc.subject.en IR spectroscopy pl
dc.subject.en zeolite CoZSM-5 pl
dc.subject.en skeletal vibrations pl
dc.description.volume 892 pl
dc.description.number 1-3 pl
dc.identifier.doi 10.1016/j.molstruc.2008.05.049 pl
dc.identifier.eissn 1872-8014 pl
dc.title.journal Journal of Molecular Structure pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl


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