Repozytorium Uniwersytetu Jagiellońskiego

Molecular switches based on cyanoferrate complexes

Molecular switches based on cyanoferrate complexes

Metadane (Dublin Core) Szaciłowski, Konrad [SAP11115985] pl Stasicka, Zofia pl 2015-09-23T07:01:12Z 2015-09-23T07:01:12Z 2002 pl
dc.identifier.issn 0010-8545 pl
dc.language eng pl
dc.title Molecular switches based on cyanoferrate complexes pl
dc.type JournalArticle pl
dc.description.physical 17-26 pl
dc.abstract.en A new system able to play the role of a molecular switch has been characterised. The system consists of the [Fe(CN) 5 NO] 2 / [Fe(CN) 5 N(O)SR] 3 complexes in equilibrium. The constituent complexes differ considerably in electronic absorption (especially in the v isible region) and undergo photochemical reactions proceeding in distinct spectral ranges and yielding different products. The equilibrium can be shifted by se v eral physical and chemical stimuli changing thereby absorption and/or modifying the photochemical beha v iour of the system. To the stimuli belong: pH, thiol concentration, ion strength, nature and concentration of cations, temperature and pressure. All these features make the system suitable for switching purposes and for different kinds of signal processing in digital, analogue and integrating circuits. As the [Fe(CN) 5 NO] 2 / [Fe(CN) 5 N(O)SR] 3 system photochemi- cally produces NO-donors and/or nitric oxide, its phototherapeutic application is considered. pl
dc.description.volume 229 pl
dc.description.number 1-2 pl
dc.identifier.doi 10.1016/S0010-8545(02)00090-5 pl
dc.identifier.eissn 1873-3840 pl
dc.title.journal Coordination Chemistry Reviews pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl

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