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To be or not to be NO in coordination chemistry? : a mechanistic approach

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To be or not to be NO in coordination chemistry? : a mechanistic approach

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dc.contributor.author Wolak, Maria pl
dc.contributor.author van Eldik, Rudi [SAP14007947] pl
dc.date.accessioned 2015-09-22T12:16:26Z
dc.date.available 2015-09-22T12:16:26Z
dc.date.issued 2002 pl
dc.identifier.issn 0010-8545 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/15760
dc.language eng pl
dc.title To be or not to be NO in coordination chemistry? : a mechanistic approach pl
dc.type JournalArticle pl
dc.description.physical 263-282 pl
dc.abstract.en In this review, the reactions of nitric oxide with selected metal complexes of biological and environmental importance are reviewed. Fundamental chemical kinetics and mechanisms that lead to the formation and decay of nitrosyl complexes are illustrated and discussed on the basis of work on Fe(II) chelate complexes and selected biomolecules such as metmyoglobin and cobalamin. In the context of common interference of higher nitrogen oxides in the studies on the interactions of nitric oxide with metal centres, the reactions of NO 2 − / HONO (in aqueous media) and NO 2 / N 2 O 3 (in aprotic media) with metal complexes are described on the basis of selected examples. Throughout the review the focus is on the mechanistic details of the binding of NO to and the release of NO from metal complexes, and the nature of the stable metal – NO complexes produced in solution. pl
dc.description.volume 230 pl
dc.description.number 1-2 pl
dc.identifier.doi 10.1016/S0010-8545(01)00472-6 pl
dc.identifier.eissn 1873-3840 pl
dc.title.journal Coordination Chemistry Reviews pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl


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