Magnetocaloric effect in a molecular magnetic sponge

2012
journal article
article
22
cris.lastimport.scopus2024-04-07T13:15:14Z
dc.abstract.enA comprehensive study of the magnetocaloric effect (MCE) in the $Mn_{2}-[Nb(CN)_{8}]$ molecular magnet with a two-step magnetic sponge behavior is reported. The structural trans- formations provoked by dehydration bring about an increase in the magnetic ordering temperature ($T_{c}$) from 43 K through to 68 K and up to 98 K. All three phases are soft isotropic ferrimagnets. The change in magnetic entropy in the par- tially and fully dehydrated phases is smaller than that in the “as synthesized” form by a factor of 0.6. The field depen- dence of MCE at $T_{c}$ is consistent with the values of the critical exponents derived from the magnetization data.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorFitta, Magdalenapl
dc.contributor.authorPełka, Robertpl
dc.contributor.authorBałanda, Mariapl
dc.contributor.authorCzapla, Mariuszpl
dc.contributor.authorMihalik, Marianpl
dc.contributor.authorPinkowicz, Dawid - 126341 pl
dc.contributor.authorSieklucka, Barbara - 131848 pl
dc.contributor.authorWasiutyński, Tadeuszpl
dc.contributor.authorZentkova, Mariapl
dc.date.accessioned2015-09-17T15:50:32Z
dc.date.available2015-09-17T15:50:32Z
dc.date.issued2012pl
dc.description.number24pl
dc.description.physical3830-3834pl
dc.description.points30pl
dc.description.volume2012pl
dc.identifier.doi10.1002/ejic.201200374pl
dc.identifier.eissn1099-0682pl
dc.identifier.issn1434-1948pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/15708
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licencebez licencji
dc.rights.uri*
dc.subject.enmolecular magnetspl
dc.subject.enmagnetic propertiespl
dc.subject.enniobiumpl
dc.subject.enmanganesepl
dc.subject.enmultifunctional materialspl
dc.subtypeArticlepl
dc.titleMagnetocaloric effect in a $Mn_{2}-pyridazine-[Nb(CN)_{8}]$ molecular magnetic spongepl
dc.title.journalEuropean Journal of Inorganic Chemistrypl
dc.typeJournalArticlepl
dspace.entity.typePublication

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