An FTIR study of the activation of CO and NO molecules on $Cu^{+}$ sites in CuZSM-5 : the effect of coadsorbed electron donor molecules

Bibliographic description

punktacja MNiSW [2012 A]: 25

title:	An FTIR study of the activation of CO and NO molecules on $Cu^{+}$ sites in CuZSM-5 : the effect of coadsorbed electron donor molecules
author:	Góra-Marek Kinga
journal title:	Vibrational Spectroscopy
volume:	58
date of publication :	2012
pages:	104-108
ISSN:	0924-2031
eISSN:	1873-3697
DOI:	10.1016/j.vibspec.2011.12.006
language:	English
journal language:	English
abstract in English:	IR spectroscopic studies evidenced that Cu + ions coordinating basic molecules (ammonia, water, and pyridine) influenced both the C O and N O bond order. The significant downshift of the stretching frequency of the N O and C O bands indicates a considerable weakening of the multiple bonds. The effect was found to be the most important for pyridine as the molecule of the strongest electron donation properties.
keywords in English:	CuZSM-5, carbon monoxide, IR spectroscopy, nitrogen monoxide
departmental parameterization:	25
affiliation:	Wydział Chemii : Zakład Chemii Nieorganicznej
type:	journal article
subtype:	academic paper

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