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An FTIR study of the activation of CO and NO molecules on Cu^{+} sites in CuZSM-5 : the effect of coadsorbed electron donor molecules
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An FTIR study of the activation of CO and NO molecules ...
Bibliographic description
| title: | An FTIR study of the activation of CO and NO molecules on Cu^{+} sites in CuZSM-5 : the effect of coadsorbed electron donor molecules |
| author: | Góra-Marek Kinga 
|
| Journal title: | Vibrational Spectroscopy |
| volume: | 58 |
| date of publication: | 2012 |
| pages: | 104-108 |
| ISSN: |
0924-2031 |
| eISSN: |
1873-3697 |
| DOI: | |
| language: | English |
| Journal language: | English |
| abstract in english: | IR spectroscopic studies evidenced that Cu + ions coordinating basic molecules (ammonia, water, and pyridine) influenced both the C O and N O bond order. The significant downshift of the stretching frequency of the N O and C O bands indicates a considerable weakening of the multiple bonds. The effect was found to be the most important for pyridine as the molecule of the strongest electron donation properties. |
| keywords in english: | CuZSM-5, carbon monoxide, IR spectroscopy, nitrogen monoxide |
| departmental parameterization: | 25 |
| affiliation: | Wydział Chemii : Zakład Chemii Nieorganicznej |
| type: | journal article |
| subtype: | academic paper |
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