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Transition metal compounds and complexes as catalysts in synthesis of acetals and orthoesters : theoretical, mechanistic and practical aspects

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Transition metal compounds and complexes as catalysts in synthesis of acetals and orthoesters : theoretical, mechanistic and practical aspects

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dc.contributor.author Krompiec, Stanisław pl
dc.contributor.author Penkala, Mateusz pl
dc.contributor.author Szczubiałka, Krzysztof [SAP11014318] pl
dc.contributor.author Kowalska, Ewelina pl
dc.date.accessioned 2015-09-11T08:41:57Z
dc.date.available 2015-09-11T08:41:57Z
dc.date.issued 2012 pl
dc.identifier.issn 0010-8545 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/15573
dc.language eng pl
dc.title Transition metal compounds and complexes as catalysts in synthesis of acetals and orthoesters : theoretical, mechanistic and practical aspects pl
dc.type JournalArticle pl
dc.description.physical 2057-2095 pl
dc.abstract.en A comprehensive review of the reports concerning the synthesis of symmetrical and, particularly, mixed acetals and orthoesters with transition metal compounds and complexes as catalysts is presented. The following methods for the synthesis of symmetric and mixed acetals are discussed: acetalization of alde- hydesorketoneswithalcoholsordiols;transacetalization;synthesisfromvinylandallylethers;synthesis via intra-orintermolecularadditionofOHgrouptoatriplebond;oxidationofprimaryalcohols;tetrahy- dropyranylation of alcohols or phenols; synthesis from epoxides and aldehydes or ketones; formation of 1,3-dioxanes by Prins cyclization of olefins with paraformaldehyde; oxidative cyclization-carbonylation of ynones; acetalization of ene-diol under Wacker-type catalysis. Reviewed is also the synthesis of mixed orthoesters via additionofalcoholsandphenolstoacroleinacetals.Presentedaremethodsoftheisolation of pure products, recycling of the catalysts (if applicable) and the advantages of the metal complexes compared to classical catalysts, Brønsted acids in particular. The relationship between the structure and reactivity was analyzed and the mechanisms of the reactions of acetal formation catalyzed by transition metal compounds and complexes were discussed. pl
dc.subject.en acetal synthesis pl
dc.subject.en transition metal catalyst pl
dc.description.volume 256 pl
dc.description.number 17-18 pl
dc.description.points 50 pl
dc.identifier.doi 10.1016/j.ccr.2012.05.006 pl
dc.identifier.eissn 1873-3840 pl
dc.title.journal Coordination Chemistry Reviews pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Fizycznej i Elektrochemii pl
dc.subtype ReviewArticle pl
dc.rights.original bez licencji pl
.pointsMNiSW [2012 A]: 50


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