Jagiellonian University Repository

Ligand and medium controlled photochemistry of iron and ruthenium mixed-ligand complexes : prospecting for versatile systems

Ligand and medium controlled photochemistry of iron ...

Show full item record

dc.contributor.author Szaciłowski, Konrad [SAP11115985] pl
dc.contributor.author Macyk, Wojciech [SAP11116781] pl
dc.contributor.author Stochel, Grażyna [SAP11011061] pl
dc.contributor.author Stasicka, Zofia pl
dc.contributor.author Sostero, Silvana pl
dc.contributor.author Traverso, Orazio pl
dc.date.accessioned 2015-09-01T11:19:16Z
dc.date.available 2015-09-01T11:19:16Z
dc.date.issued 2000 pl
dc.identifier.issn 0010-8545 pl
dc.identifier.uri http://ruj.uj.edu.pl/xmlui/handle/item/15209
dc.language eng pl
dc.title Ligand and medium controlled photochemistry of iron and ruthenium mixed-ligand complexes : prospecting for versatile systems pl
dc.type JournalArticle pl
dc.description.physical 277-297 pl
dc.abstract.en Selected Fe and Ru systems, whose photochemical behaviour is sensitive to numerous parameters, are presented. These systems, containing multiple species in equilibrium, are versatile enough to be adapted to special tasks and may also be used to model the phenomena and mechanisms occurring in nature. The role of various parameters is analysed and principal emphasis is given to the ligand sphere influence on the nature of the excited state and thereby on the photochemical mode. This is crucial in the case of Fe(II) complexes of the type [Fe(CN) 5 L] n , whereas in the carbolyl – cyclopentadienyl complexes, represented by [cpRu(CO) 2 ] 2 , the nature of the excited state is of less importance than for pentacyanofer- rates(II). The photochemistry of the carbonyl – cyclopentadienyl complexes is more suscepti- ble to the impact of the medium and the role of the secondary processes is more significant. pl
dc.description.volume 208 pl
dc.description.number 1 pl
dc.identifier.doi 10.1016/S0010-8545(00)00328-3 pl
dc.identifier.eissn 1873-3840 pl
dc.title.journal Coordination Chemistry Reviews pl
dc.language.container eng pl
dc.affiliation Wydział Chemii : Zakład Chemii Nieorganicznej pl
dc.subtype Article pl


Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)