The dynamics of plasmon-induced hot carrier creation in colloidal gold

2025
journal article
article
dc.abstract.enThe generation and dynamics of plasmon-induced hot carriers in gold nanoparticles offer crucial insights into nonequilibrium states for energy applications, yet the underlying mechanisms remain experimentally elusive. Here, we leverage ultrafast X-ray absorption spectroscopy (XAS) to directly capture hot carrier dynamics with sub-50 fs temporal resolution, providing clear evidence of plasmon decay mechanisms. We observe the sequential processes of Landau damping (~25 fs) and hot carrier thermalization (~1.5 ps), identifying hot carrier formation as a significant decay pathway. Energy distribution measurements reveal carriers in non-Fermi-Dirac states persisting beyond 500 fs and observe electron populations exceeding single-photon excitation energy, indicating the role of an Auger heating mechanism alongside traditional impact excitation. These findings deepen the understanding of hot carrier behavior under localized surface plasmon resonance, offering valuable implications for applications in photocatalysis, photovoltaics, and phototherapy. This work establishes a methodological framework for studying hot carrier dynamics, opening avenues for optimizing energy transfer processes in nanoscale plasmonic systems
dc.affiliationPion Prorektora ds. badań naukowych : Narodowe Centrum Promieniowania Synchrotronowego SOLARIS
dc.contributor.authorWach, Anna - 126105
dc.contributor.authorBericat-Vadell, Robert
dc.contributor.authorBacellar, Camila
dc.contributor.authorCirelli, Claudio
dc.contributor.authorJohnson, Philip J. M.
dc.contributor.authorCastillo, Rebeca G.
dc.contributor.authorSilveira, Vitor R.
dc.contributor.authorBroqvist, Peter
dc.contributor.authorKullgren, Jolla
dc.contributor.authorMaximenko, Alexey - 427248
dc.contributor.authorSobol, Tomasz - 391042
dc.contributor.authorPartyka-Jankowska, Ewa - 395266
dc.contributor.authorNordlander, Peter
dc.contributor.authorHalas, Naomi J.
dc.contributor.authorSzlachetko, Jakub - 432308
dc.contributor.authorSá, Jacinto
dc.date.accessioned2025-03-17T14:31:18Z
dc.date.available2025-03-17T14:31:18Z
dc.date.createdat2025-03-17T11:02:15Zen
dc.date.issued2025
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.versionostateczna wersja wydawcy
dc.description.volume16
dc.identifier.articleid2274
dc.identifier.doi10.1038/s41467-025-57657-1
dc.identifier.issn2041-1723
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/550273
dc.languageeng
dc.language.containereng
dc.rightsUdzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.typeotwarte czasopismo
dc.subtypeArticle
dc.titleThe dynamics of plasmon-induced hot carrier creation in colloidal gold
dc.title.journalNature Communications
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
The generation and dynamics of plasmon-induced hot carriers in gold nanoparticles offer crucial insights into nonequilibrium states for energy applications, yet the underlying mechanisms remain experimentally elusive. Here, we leverage ultrafast X-ray absorption spectroscopy (XAS) to directly capture hot carrier dynamics with sub-50 fs temporal resolution, providing clear evidence of plasmon decay mechanisms. We observe the sequential processes of Landau damping (~25 fs) and hot carrier thermalization (~1.5 ps), identifying hot carrier formation as a significant decay pathway. Energy distribution measurements reveal carriers in non-Fermi-Dirac states persisting beyond 500 fs and observe electron populations exceeding single-photon excitation energy, indicating the role of an Auger heating mechanism alongside traditional impact excitation. These findings deepen the understanding of hot carrier behavior under localized surface plasmon resonance, offering valuable implications for applications in photocatalysis, photovoltaics, and phototherapy. This work establishes a methodological framework for studying hot carrier dynamics, opening avenues for optimizing energy transfer processes in nanoscale plasmonic systems
dc.affiliation
Pion Prorektora ds. badań naukowych : Narodowe Centrum Promieniowania Synchrotronowego SOLARIS
dc.contributor.author
Wach, Anna - 126105
dc.contributor.author
Bericat-Vadell, Robert
dc.contributor.author
Bacellar, Camila
dc.contributor.author
Cirelli, Claudio
dc.contributor.author
Johnson, Philip J. M.
dc.contributor.author
Castillo, Rebeca G.
dc.contributor.author
Silveira, Vitor R.
dc.contributor.author
Broqvist, Peter
dc.contributor.author
Kullgren, Jolla
dc.contributor.author
Maximenko, Alexey - 427248
dc.contributor.author
Sobol, Tomasz - 391042
dc.contributor.author
Partyka-Jankowska, Ewa - 395266
dc.contributor.author
Nordlander, Peter
dc.contributor.author
Halas, Naomi J.
dc.contributor.author
Szlachetko, Jakub - 432308
dc.contributor.author
Sá, Jacinto
dc.date.accessioned
2025-03-17T14:31:18Z
dc.date.available
2025-03-17T14:31:18Z
dc.date.createdaten
2025-03-17T11:02:15Z
dc.date.issued
2025
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.version
ostateczna wersja wydawcy
dc.description.volume
16
dc.identifier.articleid
2274
dc.identifier.doi
10.1038/s41467-025-57657-1
dc.identifier.issn
2041-1723
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/550273
dc.language
eng
dc.language.container
eng
dc.rights
Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licence
CC-BY
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.type
otwarte czasopismo
dc.subtype
Article
dc.title
The dynamics of plasmon-induced hot carrier creation in colloidal gold
dc.title.journal
Nature Communications
dc.type
JournalArticle
dspace.entity.typeen
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