Optically detected magnetic resonance study of thermal effects due to absorbing environment around nitrogen-vacancy-nanodiamond powders

2024
journal article
article
dc.abstract.enWe implanted Fe$^{+}$ ions in nanodiamond (ND) powder containing negatively charged nitrogen-vacancy (NV−) centers and studied their Raman spectra and optically detected magnetic resonance (ODMR) in various applied magnetic fields with green light (532 nm) excitation. In Raman spectra, we observed a blue shift of the NV− peak associated with the conversion of the electronic sp$^{3}$ configuration to the disordered sp$^{2}$ one typical for the carbon/graphite structure. In the ODMR spectra, we observed a red shift of the resonance position caused by local heating by an absorptive environment that recovers after annealing. To reveal the red shift mechanism in ODMR, we created a controlled absorptive environment around ND by adding iron-based Fe$_{2}$O$_{3}$ and graphitic sp$^{2}$ powders to the ND suspension. This admixture caused a substantial increase in the observed shift proportional to the applied laser power, corresponding to an increase in the local temperature by 150-180 K. This surprisingly large shift is absent in non-irradiated NV-ND powders, is associated only with the modification of the local temperature by the absorptive environment of NV-NDs and can be studied using ODMR signals of NV−.
dc.affiliationWydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.authorJani, Mona - 428866
dc.contributor.authorOrzechowska, Zuzanna - 215546
dc.contributor.authorMrózek, Mariusz - 213128
dc.contributor.authorMitura-Nowak, Marzena
dc.contributor.authorGawlik, Wojciech - 101804
dc.contributor.authorWojciechowski, Adam - 139902
dc.date.accessioned2024-05-28T14:09:43Z
dc.date.available2024-05-28T14:09:43Z
dc.date.issued2024
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number20
dc.description.versionostateczna wersja wydawcy
dc.description.volume135
dc.identifier.articleid203101
dc.identifier.doi10.1063/5.0203870
dc.identifier.eissn1089-7550
dc.identifier.issn0021-8979
dc.identifier.urihttps://ruj.uj.edu.pl/handle/item/343349
dc.languageeng
dc.language.containereng
dc.rightsUdzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.typeotwarte czasopismo
dc.subject.enmagnetic resonance
dc.subject.ennitrogen-vacancy
dc.subject.ennanodiamond
dc.subject.enthermal effects
dc.subject.plrezonans magnetyczny
dc.subject.plazot-wakancja
dc.subject.plnanodiamenty
dc.subject.plefekty termiczne
dc.subtypeArticle
dc.titleOptically detected magnetic resonance study of thermal effects due to absorbing environment around nitrogen-vacancy-nanodiamond powders
dc.title.journalJournal of Applied Physics
dc.typeJournalArticle
dspace.entity.typePublicationen
dc.abstract.en
We implanted Fe$^{+}$ ions in nanodiamond (ND) powder containing negatively charged nitrogen-vacancy (NV−) centers and studied their Raman spectra and optically detected magnetic resonance (ODMR) in various applied magnetic fields with green light (532 nm) excitation. In Raman spectra, we observed a blue shift of the NV− peak associated with the conversion of the electronic sp$^{3}$ configuration to the disordered sp$^{2}$ one typical for the carbon/graphite structure. In the ODMR spectra, we observed a red shift of the resonance position caused by local heating by an absorptive environment that recovers after annealing. To reveal the red shift mechanism in ODMR, we created a controlled absorptive environment around ND by adding iron-based Fe$_{2}$O$_{3}$ and graphitic sp$^{2}$ powders to the ND suspension. This admixture caused a substantial increase in the observed shift proportional to the applied laser power, corresponding to an increase in the local temperature by 150-180 K. This surprisingly large shift is absent in non-irradiated NV-ND powders, is associated only with the modification of the local temperature by the absorptive environment of NV-NDs and can be studied using ODMR signals of NV−.
dc.affiliation
Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego
dc.contributor.author
Jani, Mona - 428866
dc.contributor.author
Orzechowska, Zuzanna - 215546
dc.contributor.author
Mrózek, Mariusz - 213128
dc.contributor.author
Mitura-Nowak, Marzena
dc.contributor.author
Gawlik, Wojciech - 101804
dc.contributor.author
Wojciechowski, Adam - 139902
dc.date.accessioned
2024-05-28T14:09:43Z
dc.date.available
2024-05-28T14:09:43Z
dc.date.issued
2024
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.number
20
dc.description.version
ostateczna wersja wydawcy
dc.description.volume
135
dc.identifier.articleid
203101
dc.identifier.doi
10.1063/5.0203870
dc.identifier.eissn
1089-7550
dc.identifier.issn
0021-8979
dc.identifier.uri
https://ruj.uj.edu.pl/handle/item/343349
dc.language
eng
dc.language.container
eng
dc.rights
Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licence
CC-BY
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.type
otwarte czasopismo
dc.subject.en
magnetic resonance
dc.subject.en
nitrogen-vacancy
dc.subject.en
nanodiamond
dc.subject.en
thermal effects
dc.subject.pl
rezonans magnetyczny
dc.subject.pl
azot-wakancja
dc.subject.pl
nanodiamenty
dc.subject.pl
efekty termiczne
dc.subtype
Article
dc.title
Optically detected magnetic resonance study of thermal effects due to absorbing environment around nitrogen-vacancy-nanodiamond powders
dc.title.journal
Journal of Applied Physics
dc.type
JournalArticle
dspace.entity.typeen
Publication
Affiliations

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