Aminophthalimide probes for monitoring of cationic photopolymerization by fluorescence probe technology and their effect on the polymerization kinetics

2012
journal article
article
32
dc.abstract.enThe performance of a series of phthalimide derivatives as fl uorescent probes for moni- toring of cationic photopolymerization of monomers by Fluorescence Probe Technology (FPT) has been studied in comparison to the performance of a 7-diethylamino-4- methylcoumarin (Coumarin 1) probe. It was found that the phthalimide probes are much more stable than Coumarin 1 under cationic polymerization conditions. Moreover, the aminophthalimide probes turned out to be long-wavelength sensitizers for the dia- ryliodonium photoinitiators used to initiate the polymerization process. The sensitizing effect of the probes compensates in excess the inhibiting effect of their amino groups on the cationic polymerization kinetics.pl
dc.affiliationWydział Chemii : Zakład Chemii Organicznejpl
dc.contributor.authorOrtyl, Joannapl
dc.contributor.authorGalek, Mariusz - 126293 pl
dc.contributor.authorMilart, Piotr - 130620 pl
dc.contributor.authorPopielarz, Romanpl
dc.date.accessioned2015-09-09T10:54:01Z
dc.date.available2015-09-09T10:54:01Z
dc.date.issued2012pl
dc.description.number3pl
dc.description.physical466-473pl
dc.description.points40pl
dc.description.volume31pl
dc.identifier.doi10.1016/j.polymertesting.2012.01.008pl
dc.identifier.eissn1873-2348pl
dc.identifier.issn0142-9418pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/15468
dc.languageengpl
dc.language.containerengpl
dc.rights.licencebez licencji
dc.subject.enFluorescent probespl
dc.subject.enCure monitoringpl
dc.subject.enCationic photopolymerizationpl
dc.subject.enFPTpl
dc.subtypeArticlepl
dc.titleAminophthalimide probes for monitoring of cationic photopolymerization by fluorescence probe technology and their effect on the polymerization kineticspl
dc.title.journalPolymer Testingpl
dc.typeJournalArticlepl
dspace.entity.typePublication
dc.abstract.enpl
The performance of a series of phthalimide derivatives as fl uorescent probes for moni- toring of cationic photopolymerization of monomers by Fluorescence Probe Technology (FPT) has been studied in comparison to the performance of a 7-diethylamino-4- methylcoumarin (Coumarin 1) probe. It was found that the phthalimide probes are much more stable than Coumarin 1 under cationic polymerization conditions. Moreover, the aminophthalimide probes turned out to be long-wavelength sensitizers for the dia- ryliodonium photoinitiators used to initiate the polymerization process. The sensitizing effect of the probes compensates in excess the inhibiting effect of their amino groups on the cationic polymerization kinetics.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Organicznej
dc.contributor.authorpl
Ortyl, Joanna
dc.contributor.authorpl
Galek, Mariusz - 126293
dc.contributor.authorpl
Milart, Piotr - 130620
dc.contributor.authorpl
Popielarz, Roman
dc.date.accessioned
2015-09-09T10:54:01Z
dc.date.available
2015-09-09T10:54:01Z
dc.date.issuedpl
2012
dc.description.numberpl
3
dc.description.physicalpl
466-473
dc.description.pointspl
40
dc.description.volumepl
31
dc.identifier.doipl
10.1016/j.polymertesting.2012.01.008
dc.identifier.eissnpl
1873-2348
dc.identifier.issnpl
0142-9418
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/15468
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights.licence
bez licencji
dc.subject.enpl
Fluorescent probes
dc.subject.enpl
Cure monitoring
dc.subject.enpl
Cationic photopolymerization
dc.subject.enpl
FPT
dc.subtypepl
Article
dc.titlepl
Aminophthalimide probes for monitoring of cationic photopolymerization by fluorescence probe technology and their effect on the polymerization kinetics
dc.title.journalpl
Polymer Testing
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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