Synthesis and characterization of pillared metal sulfates , (Me = Zn, Cd)

2013
journal article
article
4
cris.lastimport.wos2024-04-09T19:48:24Z
dc.abstract.enHybrid organic-inorganic materials of the type (diamine)MeSO4 (Me = Cd, Zn) [diamine = p-xylylenediamine (PXDA) or m-xylylenediamine (MXDA)] have not been described in the literature to date. Four compounds of this type, namely, (MXDA)ZnSO4 (1), (MXDA)CdSO4 (2), (PXDA)ZnSO4 (3), and (PXDA)CdSO4 (4), were synthesized by solvothermal methods. Since all compounds crystallized as very fine powders, crystal structure studies were performed using powder diffraction methods. All compounds crystallize in the orthorhombic crystal system and the cell parameters are: a = 9.8004(4) Å, b = 10.7829(3) Å, c = 4.88473(19) Å for 1; 9.8824(10), 11.0907(7), 4.9663(5) Å for 2; 9.8496(3), 21.2419(5), 4.89556(17) Å for 3; and 10.1136(4), 21.6625(3), 4.9562(2) Å for 4. The compounds with MXDA as a linker, crystallize in the space group P21ma, those with PXDA in Pnma. These hybrid materials are built of inorganic monolayers [–Me–(SO4)–] joined by organic linkers created by diamines (PXDA or MXDA). Me metal ions and SO42– anions form layers with a honeycomb structure. In addition to crystal structure, chemical analyses and SEM investigations were performed. Thermal stability of the compounds was also investigated using TG-DSC methods and XRD as a function of temperature.pl
dc.affiliationWydział Chemii : Zakład Krystalochemii i Krystalofizykipl
dc.contributor.authorLuberda-Durnaś, Katarzynapl
dc.contributor.authorMucha, Dariuszpl
dc.contributor.authorSanz-Camacho, Paulapl
dc.contributor.authorŁasocha, Wiesław - 130062 pl
dc.date.accessioned2015-06-08T11:07:21Z
dc.date.available2015-06-08T11:07:21Z
dc.date.issued2013pl
dc.description.admin[AU] Łasocha, Wiesław [SAP11010638]pl
dc.description.admin[AB] Sanz-Camacho, Paula 50000141pl
dc.description.number12-13pl
dc.description.physical2195-2201pl
dc.description.volume639pl
dc.identifier.doi10.1002/zaac.201300171pl
dc.identifier.eissn1521-3749pl
dc.identifier.issn0044-2313pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/8968
dc.languageengpl
dc.language.containergerpl
dc.rights.licencebez licencji
dc.subject.enlayered compoundspl
dc.subject.enelectron microscopypl
dc.subject.enX-ray diffractionpl
dc.subject.enorganic-inorganic hybrid compositespl
dc.subtypeArticlepl
dc.titleSynthesis and characterization of pillared metal sulfates $(diamine)MeSO_4$, (Me = Zn, Cd)pl
dc.title.journalZeitschrift für Anorganische und Allgemeine Chemiepl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T19:48:24Z
dc.abstract.enpl
Hybrid organic-inorganic materials of the type (diamine)MeSO4 (Me = Cd, Zn) [diamine = p-xylylenediamine (PXDA) or m-xylylenediamine (MXDA)] have not been described in the literature to date. Four compounds of this type, namely, (MXDA)ZnSO4 (1), (MXDA)CdSO4 (2), (PXDA)ZnSO4 (3), and (PXDA)CdSO4 (4), were synthesized by solvothermal methods. Since all compounds crystallized as very fine powders, crystal structure studies were performed using powder diffraction methods. All compounds crystallize in the orthorhombic crystal system and the cell parameters are: a = 9.8004(4) Å, b = 10.7829(3) Å, c = 4.88473(19) Å for 1; 9.8824(10), 11.0907(7), 4.9663(5) Å for 2; 9.8496(3), 21.2419(5), 4.89556(17) Å for 3; and 10.1136(4), 21.6625(3), 4.9562(2) Å for 4. The compounds with MXDA as a linker, crystallize in the space group P21ma, those with PXDA in Pnma. These hybrid materials are built of inorganic monolayers [–Me–(SO4)–] joined by organic linkers created by diamines (PXDA or MXDA). Me metal ions and SO42– anions form layers with a honeycomb structure. In addition to crystal structure, chemical analyses and SEM investigations were performed. Thermal stability of the compounds was also investigated using TG-DSC methods and XRD as a function of temperature.
dc.affiliationpl
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki
dc.contributor.authorpl
Luberda-Durnaś, Katarzyna
dc.contributor.authorpl
Mucha, Dariusz
dc.contributor.authorpl
Sanz-Camacho, Paula
dc.contributor.authorpl
Łasocha, Wiesław - 130062
dc.date.accessioned
2015-06-08T11:07:21Z
dc.date.available
2015-06-08T11:07:21Z
dc.date.issuedpl
2013
dc.description.adminpl
[AU] Łasocha, Wiesław [SAP11010638]
dc.description.adminpl
[AB] Sanz-Camacho, Paula 50000141
dc.description.numberpl
12-13
dc.description.physicalpl
2195-2201
dc.description.volumepl
639
dc.identifier.doipl
10.1002/zaac.201300171
dc.identifier.eissnpl
1521-3749
dc.identifier.issnpl
0044-2313
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/8968
dc.languagepl
eng
dc.language.containerpl
ger
dc.rights.licence
bez licencji
dc.subject.enpl
layered compounds
dc.subject.enpl
electron microscopy
dc.subject.enpl
X-ray diffraction
dc.subject.enpl
organic-inorganic hybrid composites
dc.subtypepl
Article
dc.titlepl
Synthesis and characterization of pillared metal sulfates $(diamine)MeSO_4$, (Me = Zn, Cd)
dc.title.journalpl
Zeitschrift für Anorganische und Allgemeine Chemie
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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